C₄₅H₆₈O₆Si₃

Base Information

Chemical Name:C₄₅H₆₈O₆Si₃
CAS No.:1007566-86-0
Molecular Formula:C₄₅H₆₈O₆Si₃
Molecular Weight:789.288
Hs Code.:

C<sub>45</sub>H<sub>68</sub>O<sub>6</sub>Si<sub>3</sub>

Synonyms:C₄₅H₆₈O₆Si₃

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Chemical Property of C₄₅H₆₈O₆Si₃

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Technology Process of C₄₅H₆₈O₆Si₃

There total 15 articles about C₄₅H₆₈O₆Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 902782-11-0
(3R,4R,6R)-6-(tert-butyldimethylsiloxy)-1-(tert-butyldiphenylsiloxy)-3-ethenyl-4-(4-methoxybenzyloxy)-3-(triethylsiloxy)-7-octyne

: 1007566-86-0
C₄₅H₆₈O₆Si₃

Guidance literature:: (3R,4R,6R)-6-(tert-butyldimethylsiloxy)-1-(tert-butyldiphenylsiloxy)-3-ethenyl-4-(4-methoxybenzyloxy)-3-(triethylsiloxy)-7-octyne; With 2,6-dimethylpyridine; ozone; In methanol; isopropyl alcohol; at -78 ℃; for 5h;

With dimethylsulfide; In methanol; isopropyl alcohol; at 20 ℃; for 1h; Further stages.;
DOI:10.1002/anie.200600458

Reference yield:

: 902782-30-3
C₁₄H₁₈O₃

: 1007566-86-0
C₄₅H₆₈O₆Si₃

Guidance literature:: Multi-step reaction with 14 steps

1.1: LiCl; 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 0.5 h / 0 °C

1.2: 15.7 g / acetonitrile / 1 h / 20 °C

2.1: 96 percent / diisobutylaluminium hydride / tetrahydrofuran; hexane / 1 h / -78 - -60 °C

3.1: 93 percent / tBuOOH; molecular sieves 4 Angstroem; D-(-)-diisopropyl tartrate / Ti(O-iPr)4 / CH₂Cl₂ / 10 h / -20 °C

4.1: 88 percent / PPh₃; CCl₄; NaHCO₃ / 3 h / Heating

5.1: nBuLi / tetrahydrofuran; hexane / 0.33 h / -78 °C

6.1: 9.22 g / imidazole / dimethylformamide / 1 h / 20 °C

7.1: O₃; 2,6-lutidine / methanol / 2 h / -78 °C

7.2: Me₂S / methanol / 1 h / 20 °C

8.1: iPr₂NLi / tetrahydrofuran; hexane / 1 h / -78 °C

8.2: tetrahydrofuran; hexane / 0.5 h / -78 °C

9.1: 8.42 g / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

10.1: imidazole / dimethylformamide / 1 h / 20 °C

11.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 0.5 h

12.1: 7.68 g / tetrahydrofuran / 1 h / -78 °C

13.1: 91 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

14.1: O₃; 2,6-lutidine / methanol; propan-2-ol / 5 h / -78 °C

14.2: Me₂S / methanol; propan-2-ol / 1 h / 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; tert.-butylhydroperoxide; tetrachloromethane; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; 4 A molecular sieve; diisobutylaluminium hydride; sodium hydrogencarbonate; D-(-)-diisopropyl tartrate; ozone; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; triphenylphosphine; lithium chloride; lithium diisopropyl amide; titanium(IV) isopropylate; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide; isopropyl alcohol; acetonitrile; 1.2: Horner-Wadsworth-Emmons reaction / 3.1: Sharpless asymmetric epoxidation / 11.1: Swern oxidation;
DOI:10.1002/anie.200600458

Reference yield:

: 902782-31-4
(2E,5R,6E)-5-(4-methoxybenzyloxy)-2,6-octadien-1-ol

: 1007566-86-0
C₄₅H₆₈O₆Si₃

Guidance literature:: Multi-step reaction with 12 steps

1.1: 93 percent / tBuOOH; molecular sieves 4 Angstroem; D-(-)-diisopropyl tartrate / Ti(O-iPr)4 / CH₂Cl₂ / 10 h / -20 °C

2.1: 88 percent / PPh₃; CCl₄; NaHCO₃ / 3 h / Heating

3.1: nBuLi / tetrahydrofuran; hexane / 0.33 h / -78 °C

4.1: 9.22 g / imidazole / dimethylformamide / 1 h / 20 °C

5.1: O₃; 2,6-lutidine / methanol / 2 h / -78 °C

5.2: Me₂S / methanol / 1 h / 20 °C

6.1: iPr₂NLi / tetrahydrofuran; hexane / 1 h / -78 °C

6.2: tetrahydrofuran; hexane / 0.5 h / -78 °C

7.1: 8.42 g / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

8.1: imidazole / dimethylformamide / 1 h / 20 °C

9.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 0.5 h

10.1: 7.68 g / tetrahydrofuran / 1 h / -78 °C

11.1: 91 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

12.1: O₃; 2,6-lutidine / methanol; propan-2-ol / 5 h / -78 °C

12.2: Me₂S / methanol; propan-2-ol / 1 h / 20 °C

With 1H-imidazole; 2,6-dimethylpyridine; tert.-butylhydroperoxide; tetrachloromethane; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; 4 A molecular sieve; sodium hydrogencarbonate; D-(-)-diisopropyl tartrate; ozone; dimethyl sulfoxide; triethylamine; triphenylphosphine; lithium diisopropyl amide; titanium(IV) isopropylate; In tetrahydrofuran; methanol; hexane; dichloromethane; N,N-dimethyl-formamide; isopropyl alcohol; 1.1: Sharpless asymmetric epoxidation / 9.1: Swern oxidation;
DOI:10.1002/anie.200600458