8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

Base Information

Chemical Name:8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline
CAS No.:1005760-70-2
Molecular Formula:C₃₈H₃₄N₈O₄
Molecular Weight:666.739
Hs Code.:

Synonyms:8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

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Chemical Property of 8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

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Technology Process of 8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

There total 1 articles about 8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1153633-14-7
8,8'-(4-(2-(2-bromoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

: 1005760-70-2
8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

Guidance literature:: With sodium azide; In dimethyl sulfoxide; at 40 ℃; for 16h;

Reference yield: 84.0%

: 17084-13-8
potassium hexafluorophosphate

: 950823-68-4
35,35-dimethyl-24,27,30,40,43,46-hexaoxa-9,12-diazanonacyclo[45.2.2.2^20,23.2^31,34.2^36,39.1^6,10.1^11,15.0^2,7.0^14,19]nonapentaconta-1⁽⁴⁹⁾,2,4,6⁽⁵⁹⁾,7,9,11⁽⁵⁸⁾,12,14,16,18,20,22,31,33,36,38,47,50,52,54,56-docosaene

: iron(II) tetrafluoroborate hexahydrate

: 1005760-70-2
8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

: Fe((N₃CH₂CH₂OCH₂CH₂OC₆H₄C₉H₅N)2)2((CH₃)2C₅₁H₄₂N₂O₆)⁽²⁺⁾*2PF₆^(1-)=Fe(C₃₈H₃₄N₈O₄)2((CH₃)2C₅₁H₄₂N₂O₆)(PF₆)2

Guidance literature:: In dichloromethane; acetonitrile; addn. of a soln. of Fe salt in MeCN to a soln. of cyclic ligand in CH2Cl2, stirring for 30 min at room temp., addn. of a soln. of azide in CH2Cl2 during 3 h, stirring overnight, evapn. in vac., dissolving in MeCN/H2O5:2, addn. of aq. KPF6; evapn., washing with water, dissolving in acetone, dropwise addn. to Et2O with stirring, filtration, washing with Et2O, drying in vac.;

Reference yield: 82.0%

: 17084-13-8
potassium hexafluorophosphate

: 950823-68-4
35,35-dimethyl-24,27,30,40,43,46-hexaoxa-9,12-diazanonacyclo[45.2.2.2^20,23.2^31,34.2^36,39.1^6,10.1^11,15.0^2,7.0^14,19]nonapentaconta-1⁽⁴⁹⁾,2,4,6⁽⁵⁹⁾,7,9,11⁽⁵⁸⁾,12,14,16,18,20,22,31,33,36,38,47,50,52,54,56-docosaene

: cobalt(II) nitrate hexahydrate

: 1005760-70-2
8,8'-(4-(2-(2-azidoethoxy)ethoxy)phenyl)-3,3'-bi-isoquinoline

: Co(C₉H₅NC₆H₄(OCH₂CH₂)2OC₆H₄)2C(CH₃)2((C₉H₅NC₆H₄OCH₂CH₂OCH₂CH₂N₃)2)2⁽³⁺⁾*3PF₆^(1-)=CoC₁₂₉H₁₁₆N₁₈O₁₄(PF₆)3

Guidance literature:: With ammonium cerium(IV) nitrate; In dichloromethane; acetonitrile; addn. of Co salt in MeCN to cyclic ligand in CH2Cl2, stirring for 30 minat room temp., addn. of ligand in CH2Cl2 during 3 h, stirring overnight , addn. of CAN in MeCN, evapn. in vac., dissolving in MeCN/H2O 5:2, addn. of aq. KPF6 satd.; evapn., washing with water, dissolving in acetone, dropwise addn. to n-pentane with stirring, filtration, washing with n-pentane, air drying;