Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5)

Base Information

• Chemical Name: Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5)
• CAS No.: 94404-84-9
• Molecular Formula: C₂₉H₂₀Fe₃N₂O₉
• Molecular Weight: 708.027
• Mol file: 94404-84-9.mol

Synonyms:Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5)

Chemical Property of Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5)

Chemical Property:

Purity/Quality:

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Technology Process of Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5)

There total 1 articles about Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

Li{Fe3(μ-NC6H5)2(CO)8(C(O)C6H5)} (94404-83-8) + trifluoromethanesulfonic acid ethyl ester (425-75-2) → Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5) (94404-84-9)

Guidance literature:

In diethyl ether; addn. of EtOTf soln. to Fe complex soln. under N2, 22°C; stirring, 16h; evapn.; chromy. (SiO2, hexane/CH2Cl2);

DOI:10.1021/ja00247a018

Reference yield: 67.0%

Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5) (94404-84-9) → Fe3(μ3-NPh)(CO)10

Guidance literature:

With CO; In benzene; byproducts: C6H5NC(OC2H5)C6H5; 22°C, 8d;

DOI:10.1021/ja00247a018

Reference yield: 67.0%

Fe3(μ-NC6H5)2(CO)8(C(OC2H5)C6H5) (94404-84-9) → Fe3(μ3-NPh)(CO)10 + N-Phenyl-benzimidic acid ethyl ester (6780-41-2)

Guidance literature:

With CO; In not given; eposure of Fe-compd. to 1 atm CO (22°C, 6 days);; yield detn. of org. product by proton NMR;;

DOI:10.1021/ja00289a049

upstream raw materials:

Li{Fe3(μ-NC6H5)2(CO)8(C(O)C6H5)}

trifluoromethanesulfonic acid ethyl ester

Downstream raw materials:

N-Phenyl-benzimidic acid ethyl ester

Refernces