N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester

Base Information

• Chemical Name: N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester
• CAS No.: 852325-27-0
• Molecular Formula: C₂₂H₃₀BrN₃O₇S
• Molecular Weight: 560.466
• Mol file: 852325-27-0.mol

Synonyms:N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester

Chemical Property of N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester

There total 1 articles about N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-bromoalanine methyl estet trifluoroacetate + Alloc-Met-Tyr-OH → N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester (852325-27-0)

Guidance literature:

With N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1021/jo0482357

Reference yield: 76.0%

N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester (852325-27-0) + hexadecanethioic S-acid (7530-93-0) → N-allyloxycarbonyl-L-methionyl-L-tyrosyl-[(S-palmitoyl)-L-cysteine] methyl ester

Guidance literature:

With sodium acetate; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; for 12h;

DOI:10.1021/jo0482357

Reference yield: 56.0%

trans,trans-farnesyl mercaptan + N-allyloxycarbonyl-L-methionyl-L-tyrosyl-L-(3-bromo-alanine) methyl ester (852325-27-0) → N-allyloxycarbonyl-L-methionyl-L-tyrosyl-[(S-farnesyl)-L-cysteine] methyl ester

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 1h;

DOI:10.1021/jo0482357