Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester

Base Information

• Chemical Name: Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester
• CAS No.: 106711-60-8
• Molecular Formula: C₃₂H₄₀O₁₂
• Molecular Weight: 616.662

Synonyms:Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester

Chemical Property of Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester

Chemical Property:

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Technology Process of Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester

There total 22 articles about Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

Acetic acid (2R,3R,4S,5R,6S)-6-allyloxy-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-methyl-tetrahydro-pyran-3-yl ester (106711-57-3) → Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester (106711-60-8)

Guidance literature:

With water; sodium acetate; acetic acid; palladium dichloride; for 18h; Ambient temperature;

Reference yield: 84.0%

Acetic acid (2R,3R,4S,5R,6R)-6-allyloxy-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-methyl-tetrahydro-pyran-3-yl ester (106711-58-4) → Acetic acid (2R,3R,4S,5R,6S)-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester (106711-60-8)

Guidance literature:

With water; sodium acetate; acetic acid; palladium dichloride; for 18h; Ambient temperature;

Reference yield: 76.0%

Acetic acid (2R,3R,4S,5R,6R)-6-allyloxy-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-methyl-tetrahydro-pyran-3-yl ester (106711-58-4) → Acetic acid (2S,3R,4S,5R,6R)-5-acetoxy-2-((2S,3R,4S,5R,6R)-5-acetoxy-4-benzyloxy-2-hydroxy-6-methyl-tetrahydro-pyran-3-yloxy)-4-benzyloxy-6-methyl-tetrahydro-pyran-3-yl ester (106711-60-8,134311-76-5)

Guidance literature:

With sodium acetate; palladium dichloride; In acetic acid; for 18h; Ambient temperature;

DOI:10.1021/ja00238a061

upstream raw materials:

Acetic acid (2R,3R,4S,5R,6R)-6-allyloxy-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-methyl-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4S,5R,6S)-6-allyloxy-4-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-methyl-tetrahydro-pyran-3-yl ester

3-O-Benzyl-6-desoxy-1,2-O-isopropyliden-α-D-gluco-hexofuranose

3-O-Benzyl-6-deoxy-D-glucose

Downstream raw materials:

C₄₇H₅₈O₁₇

C₂₆H₃₄O₉

Benzoic acid (2S,3R,4S,5R,6R)-5-acetoxy-4-benzyloxy-3-((2S,3R,4S,5R,6R)-3,5-diacetoxy-4-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-6-methyl-tetrahydro-pyran-2-yl ester

C₄₇H₅₈O₁₇

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