allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

Base Information

Chemical Name:allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside
CAS No.:701976-76-3
Molecular Formula:C₄₅H₄₉N₃O₁₂
Molecular Weight:823.897
Hs Code.:

Synonyms:allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

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Chemical Property of allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

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Technology Process of allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

There total 3 articles about allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 628281-00-5
allyl (methyl 2,4-di-O-acetyl-3-O-benzyl-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

: 701976-76-3
allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / K₂CO₃; MeOH

2: 90 percent / camphorsulfonic acid / CH₂Cl₂

With methanol; camphor-10-sulfonic acid; potassium carbonate; In dichloromethane;
DOI:10.1016/j.tetlet.2004.03.046

Reference yield:

: methyl 2,4-di-O-acetyl-3-O-benzyl-L-idopyranuronate

: 701976-76-3
allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 86 percent / K₂CO₃ / CH₂Cl₂

2: 91 percent / TMSOTf / CH₂Cl₂ / 1.5 h / 0 °C

3: 100 percent / K₂CO₃; MeOH

4: 90 percent / camphorsulfonic acid / CH₂Cl₂

With methanol; trimethylsilyl trifluoromethanesulfonate; camphor-10-sulfonic acid; potassium carbonate; In dichloromethane;
DOI:10.1016/j.tetlet.2004.03.046

Reference yield:

: methyl 2,4-di-O-acetyl-3-O-benzyl-α,β-L-idopyranyluronate trichloroacetimidate

: 701976-76-3
allyl (methyl 3-O-benzyl-2,4-O-(4-methoxybenzylidene)-α-L-idopyranosyluronate)-(1->4)-O-2-azido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / TMSOTf / CH₂Cl₂ / 1.5 h / 0 °C

2: 100 percent / K₂CO₃; MeOH

3: 90 percent / camphorsulfonic acid / CH₂Cl₂

With methanol; trimethylsilyl trifluoromethanesulfonate; camphor-10-sulfonic acid; potassium carbonate; In dichloromethane;
DOI:10.1016/j.tetlet.2004.03.046