(3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

Base Information

Chemical Name:(3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione
CAS No.:293294-37-8
Molecular Formula:C₂₂H₃₁NO₇Si
Molecular Weight:449.576
Hs Code.:

Synonyms:(3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

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Chemical Property of (3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

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Technology Process of (3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

There total 4 articles about (3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

: 413194-26-0
(4-Methoxy-phenyl)-carbamic acid (4aR,8R,8aS)-2,2-di-tert-butyl-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalen-8-yl ester

: 293294-37-8
(3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

: 293294-35-6
(3aS,4S,5aR,9aS,9bR)-8,8-Di-tert-butyl-4-hydroxy-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalen-2-one

Guidance literature:: With water; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; at 90 ℃; for 16h;
DOI:10.1021/ja012126h

Reference yield:

: 413194-26-0
(4-Methoxy-phenyl)-carbamic acid (4aR,8R,8aS)-2,2-di-tert-butyl-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-sila-naphthalen-8-yl ester

: 293294-37-8
(3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

Guidance literature:: With water; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; at 90 ℃; for 16h;
DOI:10.1002/1521-3773(20000717)39:14<2525::AID-ANIE2525>3.0.CO;2-1

Reference yield:

: 5416-93-3
4-Methoxyphenyl isocyanate

: 293294-37-8
(3aS,5aR,9aS,9bR)-8,8-Di-tert-butyl-3-(4-methoxy-phenyl)-hexahydro-1,5,7,9-tetraoxa-3-aza-8-sila-cyclopenta[a]naphthalene-2,4-dione

Guidance literature:: Multi-step reaction with 2 steps

1: DBU / CH₂Cl₂ / 25 °C

2: o-iodoxybenzoic acid; H₂O / tetrahydrofuran / 16 h / 90 °C

With water; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; 1: Addition / 2: Cycloaddition;
DOI:10.1002/1521-3773(20000717)39:14<2525::AID-ANIE2525>3.0.CO;2-1