C₂₄H₃₂O₅Si

Base Information

• Chemical Name: C₂₄H₃₂O₅Si
• CAS No.: 1612775-31-1
• Molecular Formula: C₂₄H₃₂O₅Si
• Molecular Weight: 428.601
• Mol file: 1612775-31-1.mol

Synonyms:C₂₄H₃₂O₅Si

Chemical Property of C₂₄H₃₂O₅Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₂₄H₃₂O₅Si

There total 3 articles about C₂₄H₃₂O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C25H36O6Si (1612775-30-0) → C24H32O5Si (1612775-32-2) + C24H32O5Si (1612775-31-1)

Guidance literature:

With sodium periodate; In dichloromethane; water; at 0 ℃; for 4h; Overall yield = 92 %; Overall yield = 4.43 g; Optical yield = 33.333 %de; Inert atmosphere;

DOI:10.1021/ol501446w

Reference yield:

3-tert-butyldiphenylsilyloxy-2-methylpropene (105966-43-6) → C24H32O5Si (1612775-32-2) + C24H32O5Si (1612775-31-1)

Guidance literature:

Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane / 6 h / -78 °C / Inert atmosphere

2: zinc(II) nitrate hexahydrate / acetonitrile / 5 h / 50 °C / Inert atmosphere

3: sodium periodate / dichloromethane; water / 4 h / 0 °C / Inert atmosphere

With sodium periodate; zinc(II) nitrate hexahydrate; boron trifluoride diethyl etherate; In dichloromethane; water; acetonitrile;

DOI:10.1021/ol501446w

Reference yield:

C31H44O6Si → C24H32O5Si (1612775-32-2) + C24H32O5Si (1612775-31-1)

Guidance literature:

Multi-step reaction with 2 steps

1: zinc(II) nitrate hexahydrate / acetonitrile / 5 h / 50 °C / Inert atmosphere

2: sodium periodate / dichloromethane; water / 4 h / 0 °C / Inert atmosphere

With sodium periodate; zinc(II) nitrate hexahydrate; In dichloromethane; water; acetonitrile;

DOI:10.1021/ol501446w

upstream raw materials:

3-tert-butyldiphenylsilyloxy-2-methylpropene

C₂₅H₃₆O₆Si