(S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

Base Information

Chemical Name:(S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate
CAS No.:1385029-79-7
Molecular Formula:C₁₉H₁₅F₃O₅S
Molecular Weight:412.386
Hs Code.:

Synonyms:(S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

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Technology Process of (S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

There total 2 articles about (S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 906739-21-7
methyl 2-diazo-2-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)acetate

: 673-32-5
1-Phenylprop-1-yne

: 1385029-79-7
(S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

Guidance literature:: With (R)-((4,4’-bi-1,3-benzodioxole)-5,5’-diyl)bis(bis(3,5-di-t-butyl-4-methoxyphenyl))phosphine; silver hexafluoroantimonate; In dichloromethane; at 0 ℃; for 15h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja304506g

Reference yield:

: 906739-21-7
methyl 2-diazo-2-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)acetate

: 673-32-5
1-Phenylprop-1-yne

: 1385029-79-7
(S)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

: (R)-methyl 2-methyl-3-phenyl-1-(4-(((trifluoromethyl)sulfonyl)oxy)phenyl)cycloprop-2-enecarboxylate

Guidance literature:: With silver hexafluoroantimonate; In dichloromethane; at 0 ℃; for 15h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja304506g