methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

Base Information

Chemical Name:methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate
CAS No.:132048-03-4
Molecular Formula:C₄₂H₅₈O₄Si₂
Molecular Weight:683.091
Hs Code.:

methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

Synonyms:methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

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Chemical Property of methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

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Technology Process of methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

There total 1 articles about methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 132047-97-3
methyl 7(S)-(benzyloxy)-14-<(tert-butyldiphenylsilyl)oxy>-2-methyl-9-(trimethylsilyl)tetradeca-2,8,10-trienoate

: 132048-05-6
methyl 1α-(benzyloxy)-5β-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aα,5,6,8aα-octahydronaphthalene-5α-carboxylate

: 132048-03-4
methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

: 132048-04-5
methyl 1α-(benzyloxy)-5β-methyl-6α-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aα,5,6,8aβ-octahydronaphthalene-5α-carboxylate

Guidance literature:: 2,6-di-tert-butyl-4-methyl-phenol; In toluene; at 160 ℃; Yield given. Yields of byproduct given;
DOI:10.1021/jo00003a049

Reference yield:

: 132048-03-4
methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

: 132048-13-6
1α-(benzyloxy)-8-bromo-5β-methyl-6β-<3<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-1,2,3,4,4aα,5,6,8aα-octahydronaphthalene-5α-carboxaldehyde

: 132048-11-4
1α-(benzyloxy)-8-bromo-5α-methyl-6β-<3<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxaldehyde

: 132048-12-5
1α-(benzyloxy)-8-bromo-5β-methyl-6α-<3<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-1,2,3,4,4aα,5,6,8aβ-octahydronaphthalene-5α-carboxaldehyde

Guidance literature:: 2,6-di-tert-butyl-4-methyl-phenol; In toluene; at 160 ℃; Yield given. Yields of byproduct given;
DOI:10.1021/jo00003a049

Reference yield:

: 132048-03-4
methyl 1α-(benzyloxy)-5α-methyl-6β-<3-<(tert-butyldiphenylsilyl)oxy>prop-1-yl>-8-(trimethylsilyl)-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate

: (1R,2R,4aS,5S,8aR)-5-Hydroxy-1-methyl-2-[3-((R)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-propyl]-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / EtSH, BF₃*OEt₂ / CH₂Cl₂ / 23 °C

2: 95 percent / DMAP / CH₂Cl₂ / 23 °C

With dmap; boron trifluoride diethyl etherate; ethanethiol; In dichloromethane;
DOI:10.1021/jo00003a049