((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane

Base Information

Chemical Name:((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane
CAS No.:616895-62-6
Molecular Formula:C₂₁H₃₆O₃SSi
Molecular Weight:396.667
Hs Code.:

Synonyms:((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane

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Chemical Property of ((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane

Chemical Property:

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Technology Process of ((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane

There total 8 articles about ((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 616895-62-6
((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 99 percent / Et₃N / CH₂Cl₂ / 0 °C

2: 98 percent / NaHMDS / tetrahydrofuran / 0 °C

3: 89 percent / BH₃*NH₃; LDA / tetrahydrofuran

4: PBu₃ / toluene

5: MCPBA / CH₂Cl₂

With borane-ammonia complex; tributylphosphine; sodium hexamethyldisilazane; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/S0040-4020(03)00370-3

Reference yield:

: 393530-39-7
Diazo-acetic acid (Z)-but-2-enyl ester

: 616895-62-6
((1S,2S,3R)-2-Benzenesulfonylmethyl-3-methyl-cyclopropylmethoxy)-triisopropyl-silane

Guidance literature:: Multi-step reaction with 7 steps

1: Rh[5(S)-MEPY]4 / CH₂Cl₂ / Heating

2: 93 percent / AlMe₃ / CH₂Cl₂; hexane / 72 h

3: 99 percent / Et₃N / CH₂Cl₂ / 0 °C

4: 98 percent / NaHMDS / tetrahydrofuran / 0 °C

5: 89 percent / BH₃*NH₃; LDA / tetrahydrofuran

6: PBu₃ / toluene

7: MCPBA / CH₂Cl₂

With borane-ammonia complex; tributylphosphine; trimethylaluminum; sodium hexamethyldisilazane; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; Rh[5(S)-MEPY]4; In tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1016/S0040-4020(03)00370-3