C₆₃H₁₀₇NO₁₄Si₂

Base Information

Chemical Name:C₆₃H₁₀₇NO₁₄Si₂
CAS No.:856190-98-2
Molecular Formula:C₆₃H₁₀₇NO₁₄Si₂
Molecular Weight:1158.71
Hs Code.:

C<sub>63</sub>H<sub>107</sub>NO<sub>14</sub>Si<sub>2</sub>

Synonyms:C₆₃H₁₀₇NO₁₄Si₂

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Chemical Property of C₆₃H₁₀₇NO₁₄Si₂

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Technology Process of C₆₃H₁₀₇NO₁₄Si₂

There total 35 articles about C₆₃H₁₀₇NO₁₄Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 856190-97-1
C₆₃H₁₀₇NO₁₄Si₂

: 856190-98-2
C₆₃H₁₀₇NO₁₄Si₂

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - -15 ℃; for 0.0833333h;
DOI:10.1002/anie.200500174

Reference yield:

: 856191-02-1
(5R)-6-(tert-butyldimethylsilyloxy)-5-methylhex-1-ene

: 856190-98-2
C₆₃H₁₀₇NO₁₄Si₂

Guidance literature:: Multi-step reaction with 19 steps

1.1: O₃ / CH₂Cl₂ / 0.25 h / -78 °C

1.2: 88 percent / PPh₃ / CH₂Cl₂ / 4.5 h / -78 - 20 °C

2.1: Bu₂BOTf; Et₃N / CH₂Cl₂ / 60 h / -80 °C

2.2: 94 percent / phosphate buffer; aq. H₂O₂ / CH₂Cl₂; methanol / 6 h / 20 °C / pH 7.2

3.1: 99 percent / imidazole / dimethylformamide / 48 h / 40 °C

4.1: 96 percent / n-BuLi / hexane; tetrahydrofuran / 1.33 h / -78 - -15 °C

5.1: 99 percent / Et₃SiH / Pd/C / acetone / 0.5 h / 20 °C

6.1: 49 percent / AgClO₄ / Zr(Cp)2(H)(Cl) / CH₂Cl₂; toluene / 3 h / 0 - 20 °C

7.1: 97 percent / imidazole / dimethylformamide / 20 h

8.1: DDQ / CH₂Cl₂; H₂O / 3.5 h / 0 °C

9.1: 2.14 g / Bu₃P; pyridine / 3.5 h / 20 °C

10.1: 91 percent / aq. H₂O₂; PhSeSePh / diethyl ether / 29 h / -10 - 20 °C

11.1: n-BuLi / hexane; tetrahydrofuran / 0.5 h / -78 °C

11.2: 86 percent / BF₃*OEt₂ / hexane; tetrahydrofuran / 1.5 h / -78 °C

12.1: 88 percent / lithium 4,4'-di-tert-butylbiphenyl / tetrahydrofuran / 1 h / -78 °C

13.1: 98 percent / DCC; DMAP / CH₂Cl₂ / 3 h / -5 - 0 °C

14.1: 70 percent / (+/-)-camphorsulfonic acid / CH₂Cl₂; methanol / 6 h / -20 - -10 °C

15.1: tetra-n-propylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.25 h

15.2: 85 percent / 2-methyl-2-butene; NaH₂PO₄; NaClO₂ / 2-methyl-propan-2-ol; H₂O / 1 h

16.1: piperidine / dimethylformamide / 0.08 h

17.1: 76 percent / CH₂Cl₂ / 3 h / 0 - 20 °C

18.1: 71 percent / EDCI; DMAP / CH₂Cl₂ / 20 °C

19.1: 68 percent / LHMDS / tetrahydrofuran / 0.08 h / -78 - -15 °C

With piperidine; pyridine; 1H-imidazole; triethylsilane; dmap; n-butyllithium; tetrapropylammonium perruthennate; tributylphosphine; di-n-butylboryl trifluoromethanesulfonate; diphenyl diselenide; camphor-10-sulfonic acid; dihydrogen peroxide; silver perchlorate; lithium 4,4′-di-tert-butylbiphenylide; ozone; 4-methylmorpholine N-oxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane; palladium on activated charcoal; Schwartz's reagent; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene;
DOI:10.1002/anie.200500174

Reference yield:

: 856190-89-1
(2E,4R)-1-bromo-5-(4-methoxybenzyloxy)-4-methyl-2-pentene

: 856190-98-2
C₆₃H₁₀₇NO₁₄Si₂

Guidance literature:: Multi-step reaction with 16 steps

1.1: 88 percent / n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

2.1: 99 percent / aq. NaOH / methanol / 48 h / 20 °C

3.1: 49 percent / AgClO₄ / Zr(Cp)2(H)(Cl) / CH₂Cl₂; toluene / 3 h / 0 - 20 °C

4.1: 97 percent / imidazole / dimethylformamide / 20 h

5.1: DDQ / CH₂Cl₂; H₂O / 3.5 h / 0 °C

6.1: 2.14 g / Bu₃P; pyridine / 3.5 h / 20 °C

7.1: 91 percent / aq. H₂O₂; PhSeSePh / diethyl ether / 29 h / -10 - 20 °C

8.1: n-BuLi / hexane; tetrahydrofuran / 0.5 h / -78 °C

8.2: 86 percent / BF₃*OEt₂ / hexane; tetrahydrofuran / 1.5 h / -78 °C

9.1: 88 percent / lithium 4,4'-di-tert-butylbiphenyl / tetrahydrofuran / 1 h / -78 °C

10.1: 98 percent / DCC; DMAP / CH₂Cl₂ / 3 h / -5 - 0 °C

11.1: 70 percent / (+/-)-camphorsulfonic acid / CH₂Cl₂; methanol / 6 h / -20 - -10 °C

12.1: tetra-n-propylammonium perruthenate; N-methylmorpholine N-oxide / CH₂Cl₂ / 0.25 h

12.2: 85 percent / 2-methyl-2-butene; NaH₂PO₄; NaClO₂ / 2-methyl-propan-2-ol; H₂O / 1 h

13.1: piperidine / dimethylformamide / 0.08 h

14.1: 76 percent / CH₂Cl₂ / 3 h / 0 - 20 °C

15.1: 71 percent / EDCI; DMAP / CH₂Cl₂ / 20 °C

16.1: 68 percent / LHMDS / tetrahydrofuran / 0.08 h / -78 - -15 °C

With piperidine; pyridine; 1H-imidazole; dmap; sodium hydroxide; n-butyllithium; tetrapropylammonium perruthennate; tributylphosphine; diphenyl diselenide; camphor-10-sulfonic acid; dihydrogen peroxide; silver perchlorate; lithium 4,4′-di-tert-butylbiphenylide; 4-methylmorpholine N-oxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane; Schwartz's reagent; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1002/anie.200500174