1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

Base Information

Chemical Name:1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose
CAS No.:110046-91-8
Molecular Formula:C₂₃H₃₆O₅Si
Molecular Weight:420.621
Hs Code.:

Synonyms:1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

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Chemical Property of 1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

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Technology Process of 1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

There total 1 articles about 1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 33208-47-8
4-O-benzyl-1,6:2,3-dianhydro-β-D-mannopyranose

: 88392-89-6
C₁₀H₂₁LiOSi

: 110046-91-8
1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

Guidance literature:: With magnesium; ethylene dibromide; Yield given. Multistep reaction; 1.) ether, hexane, RT, 1 h, 2.) ether, hexane, RT, 4 h;
DOI:10.1021/jo00229a013

Reference yield:

: 110046-91-8
1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

: 110046-92-9
(1R,2S,3R,4R,5R)-2-Benzyloxy-4-((Z)-3-hydroxy-2-methyl-propenyl)-6,8-dioxa-bicyclo[3.2.1]octan-3-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 0.5h;
DOI:10.1021/jo00229a013

Reference yield:

: 110046-91-8
1,6-anhydro-4-O-benzyl-2C-<3'-<(tert-butyldimethylsilyl)oxy>-2'-methylprop-1'(Z)-enyl>-β-D-glucopyranose

: (2R,3S,4R,4aR,8aR)-3-Benzyloxy-2-hydroxymethyl-6-methyl-3,4,4a,8a-tetrahydro-2H,7H-pyrano[2,3-b]pyran-4-ol

Guidance literature:: Multi-step reaction with 2 steps

1: tetra-n-butylammonim fluoride / tetrahydrofuran / 0.5 h / 0 °C

2: CF₃COOH, Et₃N / 0.08 h / var. solvents, temperatures and catalysts

With tetrabutyl ammonium fluoride; triethylamine; trifluoroacetic acid; In tetrahydrofuran;
DOI:10.1021/jo00229a013