(1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ⁵,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide

Base Information

• Chemical Name: (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ⁵,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide
• CAS No.: 127793-84-4
• Molecular Formula: C₂₄H₂₆N₈OP₂S
• Molecular Weight: 536.537
• Mol file: 127793-84-4.mol

Synonyms:(1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ⁵,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide

Chemical Property of (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ⁵,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ⁵,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide

There total 9 articles about (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ⁵,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,1'-dimethyl-P-phenyl-phosphonic-dihydrazide (54529-67-8) + C16H15N4O2PS (127793-83-3) → (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ5,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide (127793-84-4)

Guidance literature:

In methanol; for 3h; Ambient temperature;

DOI:10.1021/ja00170a027

Reference yield: 90.0%

phenylthiophosphodi(methylhydrazide) (54529-68-9) + C16H15N4O3P (127793-82-2) → (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ5,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide (127793-84-4)

Guidance literature:

In methanol; for 3h; Ambient temperature;

DOI:10.1021/ja00170a027

Reference yield:

1,1'-dimethyl-P-phenyl-phosphonic-dihydrazide (54529-67-8) → (1E,5E,9E,14E)-2,4,11,13-Tetramethyl-3,12-diphenyl-3-thioxo-1,2,4,5,10,11,13,14-octaaza-3λ5,12-diphospha-cyclooctadeca-5,9,14,18-tetraene-7,16-diyne 12-oxide (127793-84-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 94 percent / methanol / 4 h / Ambient temperature

2: 20 percent / HCOOH, CuSO₄ / CH₂Cl₂ / 0.75 h / Ambient temperature

3: 90 percent / methanol / 3 h / Ambient temperature

With formic acid; copper(II) sulfate; In methanol; dichloromethane;

DOI:10.1021/ja00170a027

upstream raw materials:

1,1'-dimethyl-P-phenyl-phosphonic-dihydrazide

C₁₆H₁₅N₄O₂PS

phenylthiophosphodi(methylhydrazide)

C₁₆H₁₅N₄O₃P