3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Base Information

Chemical Name:3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal
CAS No.:90597-30-1
Molecular Formula:C₂₇H₃₃F₃O₉S
Molecular Weight:590.615
Hs Code.:

Synonyms:3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Suppliers and Price of 3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

There total 3 articles about 3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 90597-28-7
3,4:5,6-di-O-isopropylidene-ahdehydo-D-glucose dibenzyl acetal

: 90597-30-1
3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Guidance literature:: With pyridine; In dichloromethane; at -15 - 0 ℃; for 1.5h;
DOI:10.1016/0008-6215(84)85111-3

Reference yield:

: 90597-26-5
2-O-acetyl-3,4-O-isopropylidene-aldehydo-D-glucose dibenzyl acetal

: 90597-30-1
3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Guidance literature:: Multi-step reaction with 3 steps

1: p-toluensulfonic acid / dioxane / 2 h / Ambient temperature

2: Na-methoxide / methanol

3: 93 percent / pyridine / CH₂Cl₂ / 1.5 h / -15 - 0 °C

With pyridine; sodium methylate; toluene-4-sulfonic acid; In 1,4-dioxane; methanol; dichloromethane;
DOI:10.1016/0008-6215(84)85111-3

Reference yield:

: 90597-25-4
2-O-acetyl-3,4:5,6-di-O-isopropylidene-aldehydo-D-glucose dibenzyl acetal

: 90597-30-1
3,4:5,6-di-O-isopropylidene-2-O-(trifluoromethylsulfonyl)-aldehydo-D-glucose dibenzyl acetal

Guidance literature:: Multi-step reaction with 2 steps

1: Na-methoxide / methanol

2: 93 percent / pyridine / CH₂Cl₂ / 1.5 h / -15 - 0 °C

With pyridine; sodium methylate; In methanol; dichloromethane;
DOI:10.1016/0008-6215(84)85111-3