Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

Base Information

Chemical Name:Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester
CAS No.:209474-17-9
Molecular Formula:C₁₇H₂₀O₄
Molecular Weight:288.343
Hs Code.:

Synonyms:Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

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Chemical Property of Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

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Technology Process of Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

There total 17 articles about Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 337971-07-0
(R)-(Z)-2-(6-isopropenyltetrahydropyran-3-ylidene)ethyl benzoate

: 209474-17-9
Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -10 ℃; for 72h;
DOI:10.1016/S0040-4020(00)01129-7

Reference yield:

: 209474-16-8
(R)-(Z)-2-[5-(2-hydroxyethylidene)tetrahydropyran-2-yl]propan-2-ol

: 209474-17-9
Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / triethylamine / CH₂Cl₂ / 12 h / 20 °C

2: 41 percent / 4-dimethylaminopyridine; triethylamine; MsCl / CH₂Cl₂ / 2 h / 20 °C

3: 91 percent / mCPBA / CH₂Cl₂ / 72 h / -10 °C

With dmap; methanesulfonyl chloride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/S0040-4020(00)01129-7

Reference yield:

: 209474-15-7
(R)-(Z)-2-[2-(2,2,5,5-tetramethyl[1,3]dioxolan-4-yl)ethyl]but-2-ene-1,4-diol

: 209474-17-9
Benzoic acid 2-[(R)-6-(2-methyl-oxiranyl)-dihydro-pyran-(3Z)-ylidene]-ethyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 98 percent / pyridine / 2 h / 20 °C

2: 91 percent / p-TsOH; H₂O / methanol / 44 h / 20 - 50 °C

3: 1.179 g / pyridine / 15 h / 20 °C

4: K₂CO₃ / methanol / 1.5 h / 20 °C

5: 0.432 g / aq. NaOH / methanol / 20 h / 20 °C

6: 95 percent / triethylamine / CH₂Cl₂ / 12 h / 20 °C

7: 41 percent / 4-dimethylaminopyridine; triethylamine; MsCl / CH₂Cl₂ / 2 h / 20 °C

8: 91 percent / mCPBA / CH₂Cl₂ / 72 h / -10 °C

With pyridine; dmap; sodium hydroxide; water; potassium carbonate; toluene-4-sulfonic acid; methanesulfonyl chloride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane;
DOI:10.1016/S0040-4020(00)01129-7