3-diphenylthiophosphorylaniline

Base Information

• Chemical Name: 3-diphenylthiophosphorylaniline
• CAS No.: 36267-37-5
• Molecular Formula: C₁₈H₁₆NPS
• Molecular Weight: 309.371
• Mol file: 36267-37-5.mol

Synonyms:3-diphenylthiophosphorylaniline

Chemical Property of 3-diphenylthiophosphorylaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-diphenylthiophosphorylaniline

There total 4 articles about 3-diphenylthiophosphorylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

Diphenyl-<3-nitro-phenyl>-phosphinsulfid (31638-92-3) → 3-diphenylthiophosphorylaniline (36267-37-5)

Guidance literature:

With tin(II) chloride dihdyrate; In ethanol; for 9.5h; Reflux;

DOI:10.1016/j.jorganchem.2019.02.014

Reference yield:

Triphenylphosphine oxide (791-28-6) → 3-diphenylthiophosphorylaniline (36267-37-5)

Guidance literature:

Multi-step reaction with 3 steps

1: sulfuric acid; potassium nitrate / 3 h / 50 - 60 °C

2: Lawessons reagent / chlorobenzene / 3 h / Reflux

3: tin(II) chloride dihdyrate / ethanol / 9.5 h / Reflux

With Lawessons reagent; tin(II) chloride dihdyrate; sulfuric acid; potassium nitrate; In ethanol; chlorobenzene;

DOI:10.1016/j.jorganchem.2019.02.014

Reference yield:

(3-nitrophenyl)diphenylphosphine oxide (31638-87-6) → 3-diphenylthiophosphorylaniline (36267-37-5)

Guidance literature:

Multi-step reaction with 2 steps

1: Lawessons reagent / chlorobenzene / 3 h / Reflux

2: tin(II) chloride dihdyrate / ethanol / 9.5 h / Reflux

With Lawessons reagent; tin(II) chloride dihdyrate; In ethanol; chlorobenzene;

DOI:10.1016/j.jorganchem.2019.02.014

upstream raw materials:

Triphenylphosphine oxide

(3-nitrophenyl)diphenylphosphine oxide

Diphenyl-<3-nitro-phenyl>-phosphinsulfid