methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Base Information

Chemical Name:methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate
CAS No.:883143-19-9
Molecular Formula:C₄₇H₄₉NO₇
Molecular Weight:739.909
Hs Code.:

Synonyms:methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Suppliers and Price of methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

There total 3 articles about methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 883143-17-7
methyl 2-oxo-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

: 100-46-9
benzylamine

: 883143-19-9
methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Guidance literature:: With titanium tetrachloride; In diethyl ether; dichloromethane; at 0 - 20 ℃; for 8h;
DOI:10.1055/s-2005-922768

Reference yield:

: 883143-14-4
((2S,3R,4S,5R,6R)-2-Allyl-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-hydroxy-acetic acid methyl ester

: 883143-19-9
methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / DMSO; trifluoroacetic anhydride; Et₃N / CH₂Cl₂ / 2 h / -78 °C

2: 96 percent / TiCl₄ / diethyl ether; CH₂Cl₂ / 8 h / 0 - 20 °C

With titanium tetrachloride; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; In diethyl ether; dichloromethane;
DOI:10.1055/s-2005-922768

Reference yield:

: 883143-13-3
((2R,3R,4S,5R,6R)-2-Allyl-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-trimethylsilanyloxy-acetic acid methyl ester

: 883143-19-9
methyl 2-benzyl imino-2-(1-allyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / aq. TFA / tetrahydrofuran / 20 °C

2: 80 percent / DMSO; trifluoroacetic anhydride; Et₃N / CH₂Cl₂ / 2 h / -78 °C

3: 96 percent / TiCl₄ / diethyl ether; CH₂Cl₂ / 8 h / 0 - 20 °C

With titanium tetrachloride; dimethyl sulfoxide; triethylamine; trifluoroacetic acid; trifluoroacetic anhydride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1055/s-2005-922768