[IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

Base Information

Chemical Name:[IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]
CAS No.:36117-34-7
Molecular Formula:BF₄*C₄₃H₃₄BrClIrN₂OP₂
Molecular Weight:1051.08
Hs Code.:

[IrCl(NHNC<sub>6</sub>H<sub>3</sub>Br-p)(CO)(PPh<sub>3</sub>)2][BF<sub>4</sub>]

Synonyms:[IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

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Chemical Property of [IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

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Technology Process of [IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

There total 4 articles about [IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: tetrafluoroboric acid

: 36117-35-8
[Ir(CO)Cl(NNC₆H₃Br-p)(PPh₃)2]

: 36117-34-7
[IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

Guidance literature:: In diethyl ether; inert atmosphere; dropwise addn. of 48% HBF4 to suspn. of Ir-complex (tocolor change to yellow);
DOI:10.1039/DT9770000677

Reference yield: 22.0%

: 59246-46-7,14871-41-1,15318-31-7
bis(triphenylphosphine)carbonyliridium(I) chloride

: 673-40-5
4-bromobenzenediazonium tetrafluoroborate

: 36117-34-7
[IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

Guidance literature:: With ethanol; In ethanol; benzene; inert atmosphere; addn. of diazonium salt to Ir-complex (in benzene), immediate addn. of 1/3 volume of EtOH, stirring (room temp., 3 h); evapn. (reduced pressure), stirring in C6H6, collection (filtration), washing (C6H6, Et2O), dissoln. in Me2CO, crystn. on on addn. of just required amt. of Et2O (room temp.), filtration, washing (Et2O contg. Me2CO), drying (vac.); elem. anal.;
DOI:10.1039/DT9770000677

Reference yield:

: 59246-46-7,14871-41-1,15318-31-7
bis(triphenylphosphine)carbonyliridium(I) chloride

: 673-40-5
4-bromobenzenediazonium tetrafluoroborate

: 36117-34-7
[IrCl(NHNC₆H₃Br-p)(CO)(PPh₃)2][BF₄]

: [Ir(N₄(C₆H₄Br-p)2)(CO)(PPh₃)2][BF₄]

Guidance literature:: With ethanol; In ethanol; benzene; N2-atmosphere; treatment of Ir-complex (in C6H6) with diazonium salt andthen immediately with excess of EtOH;
DOI:10.1039/DT9770002124