2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

Base Information

Chemical Name:2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol
CAS No.:882680-87-7
Molecular Formula:C₆₁H₆₃N₃O₁₀
Molecular Weight:998.185
Hs Code.:

Synonyms:2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

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Chemical Property of 2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

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Technology Process of 2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

There total 4 articles about 2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 882680-85-5
2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-1-allyl-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

: 882680-87-7
2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

Guidance literature:: 2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-1-allyl-2,4,5,6-tetra-O-benzyl-L-chiro-inositol; [{Ir(cod)Ph₂PMe}2]PF₆; In tetrahydrofuran; for 1.5h;

With N-Bromosuccinimide; In tetrahydrofuran; water; for 0.166667h; Further stages.;
DOI:10.1002/chem.200500833

Reference yield:

: 882594-53-8
2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-1-O-allyl-2,4,5,6-tetra-O-benzoyl-L-chiro-inositol

: 882680-87-7
2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

Guidance literature:: Multi-step reaction with 3 steps

1.1: 100 percent / MeONa / methanol / 16 h

2.1: NaH / dimethylformamide / 0.17 h

2.2: 68 percent / dimethylformamide / -15 °C

3.1: [{Ir(cod)Ph₂PMe}2]PF₆ / tetrahydrofuran / 1.5 h

3.2: 72 percent / N-bromosuccinimide / H₂O; tetrahydrofuran / 0.17 h

With sodium methylate; sodium hydride; [{Ir(cod)Ph₂PMe}2]PF₆; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1002/chem.200500833

Reference yield:

: 882595-31-5
2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-1-allyl-L-chiro-inositol

: 882680-87-7
2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl-α-(1->3)-2,4,5,6-tetra-O-benzyl-L-chiro-inositol

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / dimethylformamide / 0.17 h

1.2: 68 percent / dimethylformamide / -15 °C

2.1: [{Ir(cod)Ph₂PMe}2]PF₆ / tetrahydrofuran / 1.5 h

2.2: 72 percent / N-bromosuccinimide / H₂O; tetrahydrofuran / 0.17 h

With sodium hydride; [{Ir(cod)Ph₂PMe}2]PF₆; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/chem.200500833