p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

Base Information

Chemical Name:p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside
CAS No.:92714-31-3
Molecular Formula:C₂₀H₂₉NO₁₀
Molecular Weight:443.451
Hs Code.:

Synonyms:p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

Suppliers and Price of p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

There total 7 articles about p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 92714-30-2
p-nitrophenyl 3-O-(2-O-acetyl-4-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

: 92714-31-3
p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

Guidance literature:: With hydrogenchloride; hydrogen; palladium on activated charcoal; In ethanol; for 16h; under 3000.2 Torr;

Reference yield:

: 6109-60-0
methyl 3,6-dideoxy-α-D-xylo-hexopyranoside

: 92714-31-3
p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) sodium hydride / 1.) DMF, 0 deg C, 30 min, 2.) 0 deg C, 6 h

2: 75 percent / sodium hydride / dimethylformamide / 6 h / 0 °C

3: 650 mg / bromotrimethylsilane / 3 h / Ambient temperature

4: 71 percent / tetraethylammonium bromide, molecular sieves 4 Angstroem / CH₂Cl₂; dimethylformamide / Ambient temperature

5: 1.) tris-(triphenylphosphine)-rodium(I) chloride, 2.) mercury(II) oxide, mercury(II) chloride / 1.) ethanol-benzene-water, reflux, 24 h, 2.) acetone-water, room temp., 16 h

6: 87 percent / pyridine / 16 h / Ambient temperature

7: 87 percent / HCl, hydrogen / Pd/C / ethanol / 16 h / 3000.2 Torr

With hydrogenchloride; Wilkinson's catalyst; trimethylsilyl bromide; 4 A molecular sieve; tetraethylammonium bromide; hydrogen; sodium hydride; mercury dichloride; mercury(II) oxide; palladium on activated charcoal; In pyridine; ethanol; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 92714-25-5
methyl 2-O-allyl-3,6-dideoxy-α-D-xylo-hexopyranoside

: 92714-31-3
p-aminophenyl 3-O-(2-O-acetyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 75 percent / sodium hydride / dimethylformamide / 6 h / 0 °C

2: 650 mg / bromotrimethylsilane / 3 h / Ambient temperature

3: 71 percent / tetraethylammonium bromide, molecular sieves 4 Angstroem / CH₂Cl₂; dimethylformamide / Ambient temperature

4: 1.) tris-(triphenylphosphine)-rodium(I) chloride, 2.) mercury(II) oxide, mercury(II) chloride / 1.) ethanol-benzene-water, reflux, 24 h, 2.) acetone-water, room temp., 16 h

5: 87 percent / pyridine / 16 h / Ambient temperature

6: 87 percent / HCl, hydrogen / Pd/C / ethanol / 16 h / 3000.2 Torr

With hydrogenchloride; Wilkinson's catalyst; trimethylsilyl bromide; 4 A molecular sieve; tetraethylammonium bromide; hydrogen; sodium hydride; mercury dichloride; mercury(II) oxide; palladium on activated charcoal; In pyridine; ethanol; dichloromethane; N,N-dimethyl-formamide;