2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane

Base Information

• Chemical Name: 2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane
• CAS No.: 1007895-18-2
• Molecular Formula: C₃₆H₅₄B₂P₂
• Molecular Weight: 570.394
• Mol file: 1007895-18-2.mol

Synonyms:2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane

Chemical Property of 2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane

There total 1 articles about 2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

dicyclohexylboron chloride (36140-19-9) + 1,2-dipotassium-1,2-diphenyldiphosphane (6002-56-8,102816-71-7) → 2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane (1007895-18-2)

Guidance literature:

In hexane; soln. of borane added dropwise at room temp. to suspn. of diphosphide inhexane; mixt. stirred for 1 h; solid filtered off, washed with hexane; concd.; crystd. at -20°C;

DOI:10.1002/anie.200704008

Reference yield: 65.0%

2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane (1007895-18-2) → (C6H5)PB2(C6H11)4 (1007852-33-6)

Guidance literature:

In hexane; byproducts: (PhP)4.5; Irradiation (UV/VIS); photolyzed (254 nm) at room temp. overnight; filtered; concd.; left at -20°C for 1 wk;

DOI:10.1002/anie.200704008

Reference yield:

2,4-diborata-1,3-diphosphonio[1.1.0]bicyclobutane (1007895-18-2) + tri-n-butyl-tin hydride (688-73-3) → trans-P2B2(cyclohexyl)4H2Ph2 (1007852-37-0) + cis-P2B2(cyclohexyl)4H2Ph2 (1007852-37-0)

Guidance literature:

In hexane; Bu3SnH added dropwise at -20°C to B compd. soln. in hexane; mixt.stirred at room temp. for 4 h; ppt. collected by filtration; washed with hexane, dried under vac.;

DOI:10.1002/anie.200704008

upstream raw materials:

dicyclohexylboron chloride

1,2-dipotassium-1,2-diphenyldiphosphane

Downstream raw materials:

(C₆H₅)PB₂(C₆H₁₁)4

trans-P₂B₂(cyclohexyl)4H₂Ph₂

cis-P₂B₂(cyclohexyl)4H₂Ph₂