tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane

Base Information

• Chemical Name: tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane
• CAS No.: 1268380-29-5
• Molecular Formula: C₂₆H₃₁F₅O₂Sn
• Molecular Weight: 589.233
• Mol file: 1268380-29-5.mol

Synonyms:tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane

Chemical Property of tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane

There total 3 articles about tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

bromopentafluorobenzene (344-04-7) + (([2,2’-bifuran]-5,5’-diyl)bis(tributylstannane)) (1268380-28-4) → 5,5’-bis(pentafluorophenyl)-2,2’-bifuran (1268380-30-8) + tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane (1268380-29-5)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 4h; Reflux; Inert atmosphere;

Reference yield:

2,2'-bifuran (5905-00-0) → tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane (1268380-29-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 - 20 °C / Inert atmosphere

1.2: 2 h / -78 - 20 °C

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 4 h / Reflux; Inert atmosphere

With n-butyllithium; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; toluene;

Reference yield:

2,2'-bifuran (5905-00-0) + tributyltin chloride (1461-22-9) → 5,5’-bis(pentafluorophenyl)-2,2’-bifuran (1268380-30-8) + tributyl(5'-(perfluorophenyl)-[2,2'-bifuran]-5-yl)stannane (1268380-29-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 - 20 °C / Inert atmosphere

1.2: 2 h / -78 - 20 °C

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 4 h / Reflux; Inert atmosphere

With n-butyllithium; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; toluene;

upstream raw materials:

2,2'-bifuran

tributyltin chloride

bromopentafluorobenzene

(([2,2’-bifuran]-5,5’-diyl)bis(tributylstannane))