N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

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Chemical Name:N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide
CAS No.:864270-54-2
Molecular Formula:C₇₀H₈₈N₂O₁₆
Molecular Weight:1213.47
Hs Code.:

<i>N</i>-allyl-<i>N</i>-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

Synonyms:N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

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Chemical Property of N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

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Technology Process of N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

There total 14 articles about N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 864270-52-0
N-allyl-N-[2-(2-azido-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

: 864270-54-2
N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

Guidance literature:: With methanol; triethylphosphine; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ol0514202

Reference yield:

: 169151-52-4
2-azidoethyl 4,6-O-benzylidene-2-deoxy-2-N-phthalimido-β-D-glucopyranoside

: 864270-54-2
N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

Guidance literature:: Multi-step reaction with 6 steps

1.1: 64 percent / NIS; TfOH / CH₂Cl₂ / 0.33 h / 0 °C

2.1: 89 percent / NaBH₃CN; HCl / tetrahydrofuran; diethyl ether / 1 h / 0 °C

3.1: 84 percent / CuBr₂; Bu₄NBr / CH₂Cl₂; dimethylformamide / 48 h / 20 °C

4.1: ethylenediamine; BuOH / 90 °C

4.2: 82 percent / methanol / 2 h / 20 °C

5.1: 76 percent / NaH; Bu₄NI / dimethylformamide / 0.5 h / 20 °C

6.1: 67 percent / Et₃P; MeOH / CH₂Cl₂ / 3 h / 20 °C

With hydrogenchloride; methanol; N-iodo-succinimide; trifluorormethanesulfonic acid; tetrabutylammomium bromide; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium cyanoborohydride; ethylenediamine; copper(ll) bromide; butan-1-ol; triethylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol0514202

Reference yield:

: 1021450-15-6
2-[(2R,3R,4R,5S,6R)-2-(2-Azido-ethoxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-isoindole-1,3-dione

: 864270-54-2
N-allyl-N-[2-(2-amino-ethoxy)-6-benzyloxymethyl-4-[3,5-bis-allyloxy-6-allyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxy]-5-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide

Guidance literature:: Multi-step reaction with 7 steps

1.1: 3.0 g / CSA / dimethylformamide / 24 h / 20 °C

2.1: 64 percent / NIS; TfOH / CH₂Cl₂ / 0.33 h / 0 °C

3.1: 89 percent / NaBH₃CN; HCl / tetrahydrofuran; diethyl ether / 1 h / 0 °C

4.1: 84 percent / CuBr₂; Bu₄NBr / CH₂Cl₂; dimethylformamide / 48 h / 20 °C

5.1: ethylenediamine; BuOH / 90 °C

5.2: 82 percent / methanol / 2 h / 20 °C

6.1: 76 percent / NaH; Bu₄NI / dimethylformamide / 0.5 h / 20 °C

7.1: 67 percent / Et₃P; MeOH / CH₂Cl₂ / 3 h / 20 °C

With hydrogenchloride; methanol; N-iodo-succinimide; trifluorormethanesulfonic acid; camphor-10-sulfonic acid; tetrabutylammomium bromide; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium cyanoborohydride; ethylenediamine; copper(ll) bromide; butan-1-ol; triethylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol0514202