methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

Base Information

Chemical Name:methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)
CAS No.:1372659-83-0
Molecular Formula:C₃₂H₄₈O₇Si
Molecular Weight:572.814
Hs Code.:

Synonyms:methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

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Chemical Property of methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

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Technology Process of methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

There total 6 articles about methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₉H₂₀O₆S

: 1372659-83-0
methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

Guidance literature:: Multi-step reaction with 4 steps

1.1: methanol; hexane; dichloromethane / 20 °C / Inert atmosphere

2.1: 2,6-dimethylpyridine / 1,2-dichloro-ethane / 20 °C / Inert atmosphere

3.1: 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 0.17 h / -60 °C / Inert atmosphere

3.2: Inert atmosphere

4.1: dichloromethane / 1.5 h / -50 - 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In methanol; hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol300634x

Reference yield:

: 1372659-96-5
methyl (phenyl 3-O-benzyl-1-thio-β-D-glucopyranosyluronate)

: 1372659-83-0
methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

Guidance literature:: Multi-step reaction with 3 steps

1.1: 2,6-dimethylpyridine / 1,2-dichloro-ethane / 20 °C / Inert atmosphere

2.1: 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 0.17 h / -60 °C / Inert atmosphere

2.2: Inert atmosphere

3.1: dichloromethane / 1.5 h / -50 - 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol300634x

Reference yield:

: 1372659-81-8
methyl (phenyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-1-thio-β-D-glucopyranosyluronate)

: 1372659-83-0
methyl (1-adamantyl 3-O-benzyl-2,4-O-di-tert-butylsilylene-β-D-glucopyranosyluronate)

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 0.17 h / -60 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: dichloromethane / 1.5 h / -50 - 0 °C / Inert atmosphere

With 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane;
DOI:10.1021/ol300634x