1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

Base Information

Chemical Name:1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime
CAS No.:331779-26-1
Molecular Formula:C₁₃H₁₇ClN₂O₃
Molecular Weight:284.743
Hs Code.:

Synonyms:1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

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Chemical Property of 1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

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Technology Process of 1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

There total 7 articles about 1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1449512-57-5
(S)-2-benzyloxycarbonylamino-3-methylbutanaldoxime

: 331779-26-1
1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

Guidance literature:: With N-chloro-succinimide; In N,N-dimethyl-formamide; at 40 ℃; for 1h;

Reference yield:

: 501-53-1,94274-21-2
benzyl chloroformate

: 331779-26-1
1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

Guidance literature:: Multi-step reaction with 5 steps

1: sodium carbonate / tetrahydrofuran; water / 16 h / 0 - 20 °C

2: triethylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate / dichloromethane / 3 h / 28 °C

3: diisobutylaluminium hydride / dichloromethane; toluene / 6 h / -78 °C / Inert atmosphere

4: sodium acetate; hydroxylamine hydrochloride / ethanol / 16 h / 80 °C

5: N-chloro-succinimide / N,N-dimethyl-formamide / 1 h / 40 °C

With N-chloro-succinimide; hydroxylamine hydrochloride; sodium acetate; diisobutylaluminium hydride; sodium carbonate; triethylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate; In tetrahydrofuran; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene;

Reference yield:

: 114744-84-2
N^α-(benzyloxycarbonyl)-N-methoxy-N-methyl-L-valinamide

: 331779-26-1
1-chloro-3-methyl-(2S)-2-phenylmethyloxycarbonylamino-butane-1-one oxime

Guidance literature:: Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / dichloromethane; toluene / 6 h / -78 °C / Inert atmosphere

2: sodium acetate; hydroxylamine hydrochloride / ethanol / 16 h / 80 °C

3: N-chloro-succinimide / N,N-dimethyl-formamide / 1 h / 40 °C

With N-chloro-succinimide; hydroxylamine hydrochloride; sodium acetate; diisobutylaluminium hydride; In ethanol; dichloromethane; N,N-dimethyl-formamide; toluene;