phenyl (2S,3S)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

Base Information

Chemical Name:phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate
CAS No.:131196-41-3
Molecular Formula:C₃₆H₄₁NO₄Si
Molecular Weight:579.811
Hs Code.:

Synonyms:phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

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Chemical Property of phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

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Technology Process of phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

There total 5 articles about phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 131196-38-8
phenyl (2S*,3S*)-benzyl<3-(1,2-dihydroxy-4-hexenyl)>carbamate

: 58479-61-1
tert-butylchlorodiphenylsilane

: 131196-41-3
phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at -40 ℃; for 1h;
DOI:10.1021/jo00001a067

Reference yield:

: 131319-74-9
(R)-2,3-di-O-isoproylideneglyceraldehyde N-benzylimine

: 131196-41-3
phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

Guidance literature:: Multi-step reaction with 4 steps

1: CCl₄ / Heating

2: pyridine / CH₂Cl₂ / 5 h / Ambient temperature

3: 61 percent / CF₃COOH / acetonitrile; H₂O / 36 h

4: 80 percent / imidazole / dimethylformamide / 1 h / -40 °C

With pyridine; 1H-imidazole; trifluoroacetic acid; In tetrachloromethane; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00001a067

Reference yield:

: 131196-36-6
(1R*,2S*,4S*)-N-benzyl-1-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-(trimethylsilyl)-3-butenylamine

: 131196-41-3
phenyl (2S*,3S*)-benzyl<3-<1-<(tert-butyldiphenylsilyl)oxy>-2-hydroxy-4-hexenyl>>carbamate

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / 5 h / Ambient temperature

2: 61 percent / CF₃COOH / acetonitrile; H₂O / 36 h

3: 80 percent / imidazole / dimethylformamide / 1 h / -40 °C

With pyridine; 1H-imidazole; trifluoroacetic acid; In dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00001a067