nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

Base Information

Chemical Name:nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin
CAS No.:380447-58-5
Molecular Formula:C₄₈H₂₆N₄Ni
Molecular Weight:717.451
Hs Code.:

Synonyms:nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

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Technology Process of nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

There total 4 articles about nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 380447-48-3
nickel(II) 2,3-diethynyl-5,10,15,20-tetraphenylporphyrin

: 1165952-92-0
cyclohexa-1,4-diene

: 380447-58-5
nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

Guidance literature:: In chlorobenzene; Ni(C10H3N2(C6H5)2CCH)2 added to Schlenk tube; dissolved in anhyd. 5 % 1,4-cyclohexadiene soln. in chlorobenzene; sealed; heated under reflux at 190°C for 8 h; cooled to room temp.; silica gel added; solvent removed under vac.; powder loaded onto silica gel column; eluted initially with 20 % toluene in cyclohexane, then CH2Cl2; green band collected; recrystd. from CH2Cl2/methanol; m.p. > 300°C;
DOI:10.1002/1521-3773(20010917)40:18<3439::AID-ANIE3439>3.0.CO;2-Z

Reference yield: 68.0%

: 380447-48-3
nickel(II) 2,3-diethynyl-5,10,15,20-tetraphenylporphyrin

: 380447-58-5
nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

Guidance literature:: In toluene; at 130 ℃; for 8h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2011.07.008

Reference yield: 56.0%

: 380447-48-3
nickel(II) 2,3-diethynyl-5,10,15,20-tetraphenylporphyrin

: 380447-58-5
nickel(II)10,15-diphenyl-piceno[20,1,2,3,4,5-fghij]porphyrin

: 1351565-35-9
Ni(C₂₀H₆N₄(C₆H₅)4(C₄H₃Cl))

: 1351565-33-7
Ni(C₂₀H₆N₄(C₆H₅)3(C₆H₄C₄H₃))

Guidance literature:: platinum(II) chloride; In toluene; mixt. of Ni complex and PtCl2 (0.1 equiv.) in toluene heated at 85-90°C for 4 h, cooled to 25°C; solvent evapd. under reduced pressure, crude product loaded on Al2O3 column; eluted with CH2Cl2/hexane;
DOI:10.1016/j.jorganchem.2011.07.008