Technology Process of IMinostilbene-10,11-dihydrodiol
There total 1 articles about IMinostilbene-10,11-dihydrodiol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
1,4-diaza-bicyclo[2.2.2]octane; potassium osmate(VI); 4-methylmorpholine N-oxide;
In
acetone;
at 20 ℃;
for 24h;
DOI:10.1039/b506409k
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 85 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / dioxane / 10 h / 15 °C
2: 55 percent / aq. NH4NO3; Cu(OAc)2 / acetic acid / 0.5 h / 80 °C
3: 85 percent / p-toluenesulfonic acid / CHCl3 / 10 h / Heating
4: 82 percent / t-BuONa; P(t-Bu)3 / Pd2(dba)3 / toluene / 8 h / Heating
With
ammonium nitrate; copper diacetate; tri-tert-butyl phosphine; toluene-4-sulfonic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium t-butanolate;
tris(dibenzylideneacetone)dipalladium (0);
In
1,4-dioxane; chloroform; acetic acid; toluene;
DOI:10.1039/b506409k
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 85 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / dioxane / 10 h / 15 °C
2: 55 percent / aq. NH4NO3; Cu(OAc)2 / acetic acid / 0.5 h / 80 °C
3: 85 percent / p-toluenesulfonic acid / CHCl3 / 10 h / Heating
4: 87 percent / t-BuONa; P(t-Bu)3 / Pd2(dba)3 / toluene / 8 h / Heating
With
ammonium nitrate; copper diacetate; tri-tert-butyl phosphine; toluene-4-sulfonic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium t-butanolate;
tris(dibenzylideneacetone)dipalladium (0);
In
1,4-dioxane; chloroform; acetic acid; toluene;
DOI:10.1039/b506409k
