(2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether

Base Information

Chemical Name:(2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether
CAS No.:1049699-32-2
Molecular Formula:C₃₁H₄₃BrO₃Si
Molecular Weight:571.67
Hs Code.:

Synonyms:(2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether

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Chemical Property of (2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether

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Technology Process of (2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether

There total 1 articles about (2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1049699-30-0
(2R,3R,6E,10R,11R)-12-(tert-butyldiphenylsilyloxy)-2,6,10-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-ol

: 1049699-32-2
(2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether

Guidance literature:: With carbon tetrabromide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In dichloromethane; at 0 ℃;
DOI:10.1021/jo801188w

Reference yield: 85.0%

: 1049699-32-2
(2R,3R,6E,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;10,11-bis(epoxy)-6-dodecen-1-yl tetr-butyldiphenylsilyl ether

: 1049699-33-3
(2R,3R,6R,7R,10R,11S)-12-bromo-3,7,11-trimethyl-2,3;6,7;10,11-triepoxydodecyl tetr-butyldiphenylsilyl ether

Guidance literature:: With borax; Oxone; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; In water; acetonitrile; at 0 ℃; for 1.5h;
DOI:10.1021/jo801188w