{meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride

Base Information

• Chemical Name: {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride
• CAS No.: 1351286-94-6
• Molecular Formula: C₆₈H₆₈ClN₄O₁₂Rh
• Molecular Weight: 1271.67
• Mol file: 1351286-94-6.mol

Synonyms:{meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride

Chemical Property of {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride

Chemical Property:

Purity/Quality:

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• Hazard Codes: 

MSDS Files:

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Technology Process of {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride

There total 2 articles about {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

5,10,15,20-tetra-[4-(4-ethoxy-4-oxobutoxy)phenyl]-porphyrin → {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride (1351286-94-6)

Guidance literature:

With rhodium(III) chloride; In benzonitrile; for 3h; Inert atmosphere; Reflux;

DOI:10.1002/ejic.201100668

Reference yield: 98.0%

(C2H5OOC(CH2)3OC6H4)4C20H10N4 + rhodium(III)chloride (10049-07-7) → (C2H5OOC(CH2)3OC6H4)4C20H8N4RhCl (1351286-94-6)

Guidance literature:

In benzonitrile; (N2), porphyrin refluxed in benzonitrile for 5 min, treated with 2 equiv. of RhCl3, refluxed for 3 h; cooled, dried (vac.) with heating,treated with CH2Cl2, washed (aq.NaCl),org. layer dried (Na2SO4), filtered, concd., chromy.(silica gel - CH2Cl 2/EtOH 100:1), elem. anal.;

DOI:10.1002/ejic.201100668

Reference yield:

{meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}rhodium(III) chloride (1351286-94-6) → C60H48ClN4O12Rh(4-)*4K(1+)

Guidance literature:

With water; potassium hydroxide; In tetrahydrofuran; methanol; at 20 ℃; for 24h;

DOI:10.1002/ejic.201100668

upstream raw materials:

rhodium(III)chloride

Refernces

• 1、 Stangel, Christina,Charalambidis, Georgios,Varda, Varvara,Coutsolelos, Athanassios G.,Kostas, Ioannis D.. "Aqueous-organic biphasic hydrogenation of trans-cinnamaldehyde catalyzed by rhodium and ruthenium phosphane-free porphyrin complexes". experimental part. p. 4709 - 4716. Retrieved 2011/12/01.