B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

Base Information

Chemical Name:B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene
CAS No.:75258-92-3
Molecular Formula:C₂₁H₂₂O₃
Molecular Weight:322.404
Hs Code.:

Synonyms:B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

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Chemical Property of B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

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Technology Process of B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

There total 7 articles about B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: B/C-cis-1,2-trans-2-Carbomethoxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

: 75258-92-3
B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

Guidance literature:: With potassium hydroxide; In methanol; for 5h; Heating;

Reference yield:

: 5111-70-6
5-methoxy-1-indanone

: 75258-92-3
B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

Guidance literature:: Multi-step reaction with 6 steps

1: 88 percent / 4percent KOH / ethanol / 1 h / Ambient temperature

2: 75 percent / NaH / methanol / 1) reflux, 3 h 2) room temperature

3: 68 percent / p-TsOH / benzene / 10 h / Heating

4: 62 percent / Raney nickel / methanol / 2.5 h / Heating

5: 100 percent / H₂ / 10percent Pd-C / ethyl acetate / Ambient temperature

6: 78 percent / 15percent KOH / methanol / 5 h / Heating

With potassium hydroxide; hydrogen; nickel; sodium hydride; toluene-4-sulfonic acid; palladium on activated charcoal; In methanol; ethanol; ethyl acetate; benzene;

Reference yield:

: 5111-69-3
5-methoxyindane

: 75258-92-3
B/C-cis-1,2-trans-2-Carboxy-7-methoxy-1-phenyl-1,2,3,4,4a,9a-hexahydrofluorene

Guidance literature:: Multi-step reaction with 7 steps

1: 68 percent / CrO₃ / acetic acid; propionic acid; H₂O / 1) 5 - 10 deg C, 1 h 2) room temperature

2: 88 percent / 4percent KOH / ethanol / 1 h / Ambient temperature

3: 75 percent / NaH / methanol / 1) reflux, 3 h 2) room temperature

4: 68 percent / p-TsOH / benzene / 10 h / Heating

5: 62 percent / Raney nickel / methanol / 2.5 h / Heating

6: 100 percent / H₂ / 10percent Pd-C / ethyl acetate / Ambient temperature

7: 78 percent / 15percent KOH / methanol / 5 h / Heating

With chromium(VI) oxide; potassium hydroxide; hydrogen; nickel; sodium hydride; toluene-4-sulfonic acid; palladium on activated charcoal; In methanol; ethanol; water; acetic acid; propionic acid; ethyl acetate; benzene;