(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

Base Information

Chemical Name:(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one
CAS No.:151100-96-8
Molecular Formula:C₂₃H₂₃NO₃
Molecular Weight:361.441
Hs Code.:

Synonyms:(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

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Chemical Property of (R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

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Technology Process of (R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

There total 1 articles about (R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 151100-95-7
(R)-N-(2-Ethylidinecyclohexyl)-N-benzyl-2-iodo-4,4-methylenedioxybenzamide

: 151100-96-8
(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

: cis-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

Guidance literature:: With water; potassium carbonate; tris-(o-tolyl)phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In acetonitrile; for 16h; Product distribution; Heating; other catalysts and additives, variation of condition: diastereoselectivity;
DOI:10.1016/S0040-4020(01)81882-2

Reference yield: 80.0%

: 151100-96-8
(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

: 151100-97-9
(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenanthridine

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; for 3h; Ambient temperature;
DOI:10.1016/S0040-4020(01)81882-2

Reference yield:

: 151100-96-8
(R,R)-trans-11b-Vinyl-5-benzyl-1,2,3,4,4a,11b-hexahydro<1,3>dioxolo<4,5-j>phenathridine-6(5H)-one

: 151213-71-7
(R,R)-trans-5-Benzyl-2,3,4,4a,5,6-hexahydro-1H-<1,3>dioxolo<4,5-j>phenanthridine-11b-ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / LiAlH₄ / diethyl ether / 3 h / Ambient temperature

2: 1) BH₃*Me₂S, 2) 2N aq. NaOH, 30percent aq. H₂O₂ / 1) THF, r.t., 8 h, 2) r.t., 1 h

With sodium hydroxide; lithium aluminium tetrahydride; dimethylsulfide borane complex; dihydrogen peroxide; In diethyl ether;
DOI:10.1016/S0040-4020(01)81882-2