trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

Base Information

Chemical Name:trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane
CAS No.:1424999-68-7
Molecular Formula:C₁₈H₂₉BO₄SSi
Molecular Weight:380.388
Hs Code.:

Synonyms:trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

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Chemical Property of trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

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Technology Process of trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

There total 4 articles about trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 16029-98-4
trimethylsilyl iodide

: 1424999-26-7
4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

: 1424999-68-7
trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

Guidance literature:: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

trimethylsilyl iodide; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1039/c3cc00030c

Reference yield:

: 1424999-30-3
2-(2-iodo-1-(phenylsulfonyl)propan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1424999-68-7
trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / dichloromethane / 96 h / Reflux

2.1: lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C

2.2: 3 h / 20 °C

With triethylamine; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c3cc00030c

Reference yield:

: 1950-77-2
benzenesulfonyl iodide

: 1424999-68-7
trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: dichloromethane / 12 h / 20 °C

2.1: triethylamine / dichloromethane / 96 h / Reflux

3.1: lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C

3.2: 3 h / 20 °C

With triethylamine; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c3cc00030c