C₂₃H₃₈O₅Si

Base Information

• Chemical Name: C₂₃H₃₈O₅Si
• CAS No.: 1391825-73-2
• Molecular Formula: C₂₃H₃₈O₅Si
• Molecular Weight: 422.637
• Mol file: 1391825-73-2.mol

Synonyms:C₂₃H₃₈O₅Si

Chemical Property of C₂₃H₃₈O₅Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₃₈O₅Si

There total 8 articles about C₂₃H₃₈O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

C23H37ClHgO4Si (1391825-72-1) → C23H38O5Si (1391825-73-2)

Guidance literature:

With sodium tetrahydroborate; oxygen; In N,N-dimethyl-formamide; at 20 ℃; for 4h;

DOI:10.1007/s11164-012-0702-y

Reference yield:

(1S)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)pent-4-en-1-ol (209849-12-7) → C23H38O5Si (1391825-73-2)

Guidance literature:

Multi-step reaction with 10 steps

1.1: mercury(II) diacetate / tetrahydrofuran / 2 h / 20 °C

2.1: oxygen; sodium tetrahydroborate / N,N-dimethyl-formamide / 4 h / 20 °C

3.1: sodium; naphthalene / tetrahydrofuran / 0 °C

4.1: sodium hydride / 3 h / 20 °C

5.1: sodium hydride; carbon disulfide; methyl iodide / tetrahydrofuran / 2 h / 0 °C

5.2: 3 h / 90 °C

6.1: toluene-4-sulfonic acid / tetrahydrofuran; water / 2 h / 60 °C

6.2: 10 h / 0 - 20 °C

7.1: tetrahydrofuran / 10 h / 0 - 20 °C

8.1: dmap / dichloromethane / 2 h / 20 °C

9.1: mercury(II) diacetate / tetrahydrofuran / 2 h / 20 °C

10.1: oxygen; sodium tetrahydroborate / N,N-dimethyl-formamide / 4 h / 20 °C

With carbon disulfide; dmap; sodium tetrahydroborate; naphthalene; mercury(II) diacetate; oxygen; sodium; sodium hydride; toluene-4-sulfonic acid; methyl iodide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; 5.1: |Barton-McCombie Deoxygenation / 5.2: |Barton-McCombie Deoxygenation;

DOI:10.1007/s11164-012-0702-y

Reference yield:

C12H20O6 (1424636-45-2) → C23H38O5Si (1391825-73-2)

Guidance literature:

Multi-step reaction with 7 steps

1.1: sodium hydride / 3 h / 20 °C

2.1: sodium hydride; carbon disulfide; methyl iodide / tetrahydrofuran / 2 h / 0 °C

2.2: 3 h / 90 °C

3.1: toluene-4-sulfonic acid / tetrahydrofuran; water / 2 h / 60 °C

3.2: 10 h / 0 - 20 °C

4.1: tetrahydrofuran / 10 h / 0 - 20 °C

5.1: dmap / dichloromethane / 2 h / 20 °C

6.1: mercury(II) diacetate / tetrahydrofuran / 2 h / 20 °C

7.1: oxygen; sodium tetrahydroborate / N,N-dimethyl-formamide / 4 h / 20 °C

With carbon disulfide; dmap; sodium tetrahydroborate; mercury(II) diacetate; oxygen; sodium hydride; toluene-4-sulfonic acid; methyl iodide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; 2.1: |Barton-McCombie Deoxygenation / 2.2: |Barton-McCombie Deoxygenation;

DOI:10.1007/s11164-012-0702-y

upstream raw materials:

C₁₂H₂₀O₆

(1S)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)pent-4-en-1-ol

C₁₉H₂₅ClHgO₅

C₁₉H₂₆O₆