Cr(CO)5NCC₆H₄CH₂Cl

Base Information

Chemical Name:Cr(CO)5NCC₆H₄CH₂Cl
CAS No.:88656-97-7
Molecular Formula:C₁₃H₆ClCrNO₅
Molecular Weight:343.643
Hs Code.:

Cr(CO)5NCC<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>Cl

Synonyms:Cr(CO)5NCC₆H₄CH₂Cl

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Chemical Property of Cr(CO)5NCC₆H₄CH₂Cl

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Technology Process of Cr(CO)5NCC₆H₄CH₂Cl

There total 1 articles about Cr(CO)5NCC₆H₄CH₂Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.2%

: 14780-98-4
tetraethylammonium pentacarbonyliodochromate⁽⁰⁾

: 88644-59-1
2-(chloromethyl)phenyl isocyanide

: 88656-97-7
Cr(CO)5NCC₆H₄CH₂Cl

Guidance literature:: With silver tetrafluoroborate; In acetone; under N2 or Ar, to suspn. of 1.1 equiv of Cr-complex in acetone at 0°C was added acetone soln. of 1.13 equiv of AgBF4 dropwise over 20 min, filtered, treated dropwise at 0°C with soln. of 1 equiv of ligand in acetone, stirred for 20 min; heated to room temp., evapd. to dryness under reduced pressure, extd. with Et2O, filtered, taken to dryness, dissolved in CH2Cl2, chromd. on silica gel column, eluted with Et2O, n-hexane added, concd., cooled, filtered, dried under vac.; elem. anal.;

Reference yield: 85.6%

: 88656-97-7
Cr(CO)5NCC₆H₄CH₂Cl

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 88656-99-9
Cr(CO)5(CNC₆H₄CH₂I)

Guidance literature:: In acetone; under N2 or Ar, Cr-complex was reacted with soln. of 5.9 equiv of NaI in acetone at room temp. overnight; taken to dryness, extd. with C6H6, concd., chromd. on silica gel column, eluted with Et2O, evapd., n-hexane added, cooled to -10°C;