3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Base Information

Chemical Name:3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose
CAS No.:921202-61-1
Molecular Formula:C₂₄H₃₄O₇
Molecular Weight:434.53
Hs Code.:

Synonyms:3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Suppliers and Price of 3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

There total 5 articles about 3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 921202-57-5
3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

: 106-95-6
allyl bromide

: 921202-61-1
3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Guidance literature:: 3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose; With sodium hydride; In tetrahydrofuran; for 2h; Heating;

allyl bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at 95 ℃; for 1.5h;
DOI:10.1021/jo061904r

Reference yield:

: 921202-53-1
1,2:5,6-di-O-isopropylidene-3-C-(1'-hydroxyethyl)-α-D-allo-1,4-furanose

: 921202-61-1
3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran; various solvent(s) / 1 h / 0 °C

1.2: 88 percent / tetrahydrofuran; various solvent(s) / 72 h / 20 °C

2.1: NaH / tetrahydrofuran / 2 h / Heating

2.2: 97 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / 95 °C

With sodium hydride; In tetrahydrofuran;
DOI:10.1021/jo061904r

Reference yield:

: 2847-00-9
1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose

: 921202-61-1
3-O-allyl-3-C-(2-benzyloxyethyl)-1,2:5,6-di-O-isopropylidene-D-allofuranose

Guidance literature:: Multi-step reaction with 4 steps

1.1: tetrahydrofuran; diethyl ether / 3 h / 20 °C

2.1: ozone / CH₂Cl₂ / -78 °C

2.2: NaBH₄ / CH₂Cl₂; methanol / 1.5 h / Heating

2.3: 84 percent / NH₃ / CH₂Cl₂; methanol / 8 h / Heating

3.1: NaH / tetrahydrofuran; various solvent(s) / 1 h / 0 °C

3.2: 88 percent / tetrahydrofuran; various solvent(s) / 72 h / 20 °C

4.1: NaH / tetrahydrofuran / 2 h / Heating

4.2: 97 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / 95 °C

With sodium hydride; ozone; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo061904r