C₂₄H₃₆O₅Si

Base Information

• Chemical Name: C₂₄H₃₆O₅Si
• CAS No.: 1350544-09-0
• Molecular Formula: C₂₄H₃₆O₅Si
• Molecular Weight: 432.632
• Mol file: 1350544-09-0.mol

Synonyms:C₂₄H₃₆O₅Si

Chemical Property of C₂₄H₃₆O₅Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₂₄H₃₆O₅Si

There total 1 articles about C₂₄H₃₆O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

C24H38O5Si → C24H36O5Si (1350544-09-0)

Guidance literature:

With sulfur trioxide pyridine complex; In dichloromethane; dimethyl sulfoxide; at 0 ℃; for 1.5h; Inert atmosphere;

DOI:10.1021/ol202728v

Reference yield: 76.0%

C24H36O5Si (1350544-09-0) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → C28H42O5Si (1350544-10-3) + C28H42O5Si (1350544-11-4)

Guidance literature:

C₂₄H₃₆O₅Si; With titanium tetrachloride; In toluene; at -78 ℃; for 1.17h; Inert atmosphere;

buta-1,3-diene; at -78 - 5 ℃; for 3.5h; optical yield given as %de; diastereoselective reaction;

DOI:10.1021/ol202728v

Reference yield:

C24H36O5Si (1350544-09-0) → C34H52O5Si2 (1350544-15-8)

Guidance literature:

Multi-step reaction with 5 steps

1.1: titanium tetrachloride / toluene / 1.17 h / -78 °C / Inert atmosphere

1.2: 3.5 h / -78 - 5 °C

2.1: 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide / acetonitrile / 3 h / 82 °C / Inert atmosphere

3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / 3 h / 23 °C / Inert atmosphere

4.1: diethylzinc / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere

4.2: 0.67 h / -78 - 0 °C / Inert atmosphere

4.3: 0.42 h / -78 - -20 °C / Inert atmosphere

5.1: cerium(III) chloride; lithium chloride / diethyl ether / 3.25 h / -78 °C / Inert atmosphere

5.2: 2 h / -78 - 0 °C / Inert atmosphere

With cerium(III) chloride; diethylzinc; titanium tetrachloride; 1,1,1,3,3,3-hexamethyl-disilazane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium iodide; lithium chloride; In tetrahydrofuran; diethyl ether; toluene; acetonitrile; 1.1: Diels-Alder reaction / 1.2: Diels-Alder reaction;

DOI:10.1021/ol202728v

Downstream raw materials:

C₃₁H₅₀O₅Si₂

C₂₈H₄₀O₅Si

C₃₆H₅₂O₆Si₂

C₃₄H₅₂O₅Si₂