1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3

Base Information

• Chemical Name: 1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3
• CAS No.: 1039040-49-7
• Molecular Formula: C₆₃H₄₆N₂OsP₂
• Molecular Weight: 1083.22
• Mol file: 1039040-49-7.mol

Synonyms:1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3

Chemical Property of 1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3

Chemical Property:

Purity/Quality:

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Technology Process of 1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3

There total 1 articles about 1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

(η5-cyclopentadienyl)bis(triphenylphosphine)osmium(II)(Br) (34742-23-9) + 1,3-(HCC)-5-(bpyCC)C6H3 (1039040-48-6) → 1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3 (1039040-49-7) + (H(C5H3N)2C2C6H3(C2)2)[(PPh3)2(η5-C5H5)Os]2

Guidance literature:

With (NH₄)PF₆; sodium; In methanol; under N2 atm. mixt. Os complex, ligand, anf (NH4)PF6 in MeOH was heated under reflux for 3 h; react. mixt. was cooled to room temp., Na metal was added, solvent was removed in vacuo, residue was purified by column chromy. on alumina (Et2O- petroleum ether); elem. anal.;

DOI:10.1021/om800232m

Reference yield: 72.0%

1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3 (1039040-49-7) + 1-(η5-cyclopentadienyl)Fe(η5-C5H4CC)-3-[(4,4'-di-tert-butyl-2,2'-bipyridine)(CO)3ReCC]-5-[trans-Cl(PPh3)2PtCC]C6H3 → trans-[(PPh3)2Pt(1-(FcCC)-3-[(t-Bu2bpy)(CO)3ReCC]-5-(CC)C6H3)(1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpy-CC)-5-(CC)C6H3)]

Guidance literature:

With CuI; diethylamine; In chloroform; under N2 atm. to soln. Pt-Re-Fe and Os complexes in CHCl3 Et2NH and CuI were added and stirred at 30-40°C for 3.5 h; react mixt. was cooled to room temp., volatiles were removed in vacuo, residue was cromd. on silica (CH2Cl2-toluene 3:1); elem. anal.;

DOI:10.1021/om800232m

Reference yield: 63.0%

1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(HCC)C6H3 (1039040-49-7) + 1-[(t-Bu2bpy)(CO)3ReCC]-3-[(η2-dppf)(η5-C5H5)RuCC]-5-[trans-(Ph3P)2(Cl)PtCC]C6H3 → trans-[(PPh3)2Pt(1-[(t-Bu2bpy)(CO)3ReCC]-3-[(η2-dppf)(η5-C5H5)RuCC]-5-(CC)C6H3)(1-[(Ph3P)2(η5-C5H5)OsCC]-3-(bpyCC)-5-(CC)C6H3)]

Guidance literature:

With CuI; diethylamine; In chloroform; under N2 atm. to soln. Re-Ru-Pt and Os complexes in CHCl3-Et2NH CuI was added and stirred for 4 h at 30°C; volatiles were removed in vacuo, column chromy. on alumina (CH2Cl2-toluene 5:1); elem. anal.;

DOI:10.1021/om800232m

upstream raw materials:

(η5-cyclopentadienyl)bis(triphenylphosphine)osmium(II)(Br)

1,3-(HCC)-5-(bpyCC)C₆H₃