diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate

Base Information

• Chemical Name: diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate
• CAS No.: 1189125-19-6
• Molecular Formula: C₁₇H₂₇O₆P
• Molecular Weight: 358.372
• Mol file: 1189125-19-6.mol

Synonyms:diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate

Chemical Property of diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate

There total 1 articles about diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(Z)-5-(4-methoxybenzyloxy)pent-3-en-2-ol (1189125-40-3) + diethyl chlorophosphate (814-49-3) → diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate (1189125-19-6)

Guidance literature:

With 1-methyl-1H-imidazole; In diethyl ether; at 20 ℃; Cooling with ice;

DOI:10.1021/jo901728b

Reference yield:

diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate (1189125-19-6) + trimethylsilylacetylene (1066-54-2) → C13H17BrO2 (1189125-55-0) + C13H17BrO2 + C18H26O2Si (1189125-53-8)

Guidance literature:

trimethylsilylacetylene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h;

With copper(I) bromide dimethylsulfide complex; magnesium bromide; In tetrahydrofuran; hexane; at 0 ℃; for 1h;

diethyl (Z)-5-(4-methoxybenzyloxy)pent-3-en-2-yl phosphate; In tetrahydrofuran; hexane; at 20 ℃; for 81h;

DOI:10.1021/jo901728b

upstream raw materials:

(Z)-5-(4-methoxybenzyloxy)pent-3-en-2-ol

diethyl chlorophosphate

Downstream raw materials:

C₁₃H₁₇BrO₂

C₁₈H₂₆O₂Si