trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

Base Information

Chemical Name:trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃
CAS No.:945679-60-7
Molecular Formula:C₆₂H₇₃F₅P₂PtSi
Molecular Weight:1198.37
Hs Code.:

trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P(CH<sub>2</sub>)8CH=CH<sub>2</sub>)2Pt(C<sub>2</sub>)3SiEt<sub>3</sub>

Synonyms:trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

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Chemical Property of trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

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Technology Process of trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

There total 2 articles about trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1777-03-3
2-triethylsilylacetylene

: 945679-65-2
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)2H

: 945679-60-7
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

: 945679-57-2
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

Guidance literature:: With catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; O₂; In acetone; O2 was bubbled through a soln. of complex and silane-compound in acetonewith stirring, the soln. was heated to 65°C, a soln. of CuCl/TME DA in acetone, stirred for 0.5 h, was added in portions over 2 h, 0.5 h; the solvent was rotary evapd., extd. with hexanes, then toluene, passed through an alumina column (toluene), rotary evapd., chromd. on silica gel column (90:10 v/v hexanes/CH2Cl2), the solvent was removed by oil pumping vac.; as oil; elem. anal.;
DOI:10.1021/ja071612n

Reference yield:

: 647012-10-0
trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

: 945679-60-7
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

Guidance literature:: Multi-step reaction with 2 steps

1: HN(C₂H₅)2 / copper(l) iodide / dichloromethane; tetrahydrofuran

2: catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; O₂ / acetone

With HN(C₂H₅)2; catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; O₂; copper(l) iodide; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/ja071612n

Reference yield: 64.0%

: 945679-60-7
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

: 945679-61-8
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)6Pt(Ph₂P(CH₂)8CH=CH₂)2(C₆F₅)

Guidance literature:: With catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; (C₄H₉)4NF; O₂; In tetrahydrofuran; water; acetone; diamine was added to CuCl in acetone, stirred for 0.5 h, (n-C4H9)4NF in THF/5 wt%H2O was added to a soln. of Pt-complex in acetone with stirring, after 20 min (CH3)3SiCl was added, O2 was bubbled, heated to 65°C, Cu-soln. was added over 4 h, 0.5h; the solvent was removed by oil pump vac., the residue was extd. with hexanes, then toluene, filtered through an alumina column (toluene), rotaryevapd., chromd. on a silica gel column (90:10 hexanes/CH2Cl2), vac.-pum ping; as oil; elem. anal.;
DOI:10.1021/ja071612n