Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene

Base Information

Chemical Name:Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene
CAS No.:14553-78-7
Molecular Formula:C₃₂H₃₂
Molecular Weight:416.606
Hs Code.:
DSSTox Substance ID:DTXSID70496779
Nikkaji Number:J665.400B
Mol file:14553-78-7.mol

Synonyms:14553-78-7;[2.2.2.2]metacyclophane;DTXSID70496779;Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene

Suppliers and Price of Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene

Chemical Property:

XLogP3:8.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:416.250401021
Heavy Atom Count:32
Complexity:400

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2=CC(=CC=C2)CCC3=CC(=CC=C3)CCC4=CC=CC(=C4)CCC5=CC=CC1=C5

Technology Process of Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene

There total 3 articles about Pentacyclo[23.3.1.1~4,8~.1~11,15~.1~18,22~]dotriaconta-1(29),4(32),5,7,11(31),12,14,18(30),19,21,25,27-dodecaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.4%

: 626-15-3
1,3-bis-(bromomethyl)benzene

: 4662-96-8
1,2-di-m-tolylethane

: 14553-78-7
<2.2.2.2>metacyclophane

: 1,3-bis<2-(3-methylphenyl)ethyl>benzene

: 3,3'-bis<2-(3-methylphenyl)ethyl>dibenzyl

Guidance literature:: With samarium diiodide; In tetrahydrofuran; at 0 ℃; for 2h; Further byproducts given;

Reference yield: 14.6%

: 626-16-4
3-(chloromethyl)benzyl chloride

: 4662-96-8
1,2-di-m-tolylethane

: 14553-78-7
<2.2.2.2>metacyclophane

: 1,3-bis<2-(3-methylphenyl)ethyl>benzene

: 3,3'-bis<2-(3-methylphenyl)ethyl>dibenzyl

Guidance literature:: With samarium diiodide; In tetrahydrofuran; for 4h; Further byproducts given; Ambient temperature;

Reference yield: 7.7%

: 626-15-3
1,3-bis-(bromomethyl)benzene

: 51744-98-0,2319-97-3,96290-39-0
[2.2]Metacyclophan

: 4662-96-8
1,2-di-m-tolylethane

: 14553-78-7
<2.2.2.2>metacyclophane

: 13612-55-0
<2.2.2>metacyclophane

: 1,3-bis<2-(3-methylphenyl)ethyl>benzene

: 3,3'-bis<2-(3-methylphenyl)ethyl>dibenzyl

Guidance literature:: With samarium diiodide; In tetrahydrofuran; for 0.166667h; Product distribution; Ambient temperature; other bis(bromomethyl)arenes;