Technology Process of (R)-1-(benzylsulfinyl)-2-methylbenzene
There total 3 articles about (R)-1-(benzylsulfinyl)-2-methylbenzene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
benzyl (2-methyl phenyl) sulfide;
With
manganese(II) triflate; N1,N2-bis(2-((R)-4-isopropyl-4,5-dihydrooxazol-2-yl)phenyl)benzene-1,2-diamine;
In
acetonitrile;
at 20 ℃;
for 6h;
Inert atmosphere;
Green chemistry;
With
1-Adamantanecarboxylic acid; dihydrogen peroxide;
In
isopropyl alcohol; acetonitrile;
at -20 ℃;
for 2h;
enantioselective reaction;
Inert atmosphere;
Green chemistry;
DOI:10.1039/c4ra09832c
- Guidance literature:
-
With
manganese(II) triflate; 1-Adamantanecarboxylic acid; C30H34N4O2; dihydrogen peroxide;
In
isopropyl alcohol; acetonitrile;
at -20 ℃;
for 2h;
- Guidance literature:
-
benzyl (2-methyl phenyl) sulfide;
With
copper acetylacetonate; (S)-2-(N-3',5'-dichlorosalicylidene)-amino-3,3-dimethyl-1-butanol;
In
methanol; hexane;
at 20 ℃;
for 0.0833333h;
With
dihydrogen peroxide;
In
methanol; hexane;
at 20 ℃;
for 16h;
optical yield given as %ee;
enantioselective reaction;
DOI:10.1021/jo2026178
