(1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

Base Information

Chemical Name:(1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester
CAS No.:117487-19-1
Molecular Formula:C₁₈H₁₈O₃
Molecular Weight:282.339
Hs Code.:

Synonyms:(1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

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Chemical Property of (1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

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Technology Process of (1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

There total 5 articles about (1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 22979-36-8
methyl 2-diazo-2-(4-methoxypheny)acetate

: 117487-19-1
(1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

: (1S)-(4-methoxyphenyl)-(2R)-phenylcyclopropanecarboxylic acid methyl ester

Guidance literature:: With benzoic acid methyl ester; {1,3-di-[(S)-prolin-5-yl]benzene}-based dirhodium; 4 A molecular sieve; In dichloromethane; at 23 ℃; for 24h; Title compound not separated from byproducts;
DOI:10.1021/ol034002a

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 22979-36-8
methyl 2-diazo-2-(4-methoxypheny)acetate

: 117487-19-1
(1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

: methyl 1-(4-methoxyphenyl)-2-phenylcyclopropane-1-carboxylate

: (1S)-(4-methoxyphenyl)-(2R)-phenylcyclopropanecarboxylic acid methyl ester

Guidance literature:: With [Rh₂(acam)((R)-TPCP)₃]; In dichloromethane; at 20 ℃; for 6h; Temperature; Overall yield = 78 percent; Overall yield = 53 mg; enantioselective reaction; Catalytic behavior; Schlenk technique; Inert atmosphere;
DOI:10.1002/anie.202004377

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 22979-36-8
methyl 2-diazo-2-(4-methoxypheny)acetate

: methyl 1-(p-methoxyphenyl)-2-phenylcyclopropanecarboxylate

: 117487-19-1
(1R)-(4-methoxyphenyl)-(2S)-phenylcyclopropanecarboxylic acid methyl ester

: (1S)-(4-methoxyphenyl)-(2R)-phenylcyclopropanecarboxylic acid methyl ester

Guidance literature:: With dirhodium(II) tetrakis[(S)-N-(4-tert-butylphthalimido)-tert-leucinate]; at 20 ℃; Reagent/catalyst; Overall yield = 85 %; stereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.201504817