(4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

Base Information

Chemical Name:(4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid
CAS No.:147461-28-7
Molecular Formula:C₂₅H₃₆O₆SSi
Molecular Weight:492.709
Hs Code.:

Synonyms:(4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

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Chemical Property of (4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

Chemical Property:

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Technology Process of (4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

There total 4 articles about (4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 131722-62-8
1,2:5,6-dianhydro-3,4-dideoxy-erythro-hexitol

: 147461-28-7
(4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

Guidance literature:: Multi-step reaction with 4 steps

1: Vitride / tetrahydrofuran / 0 deg C -> r.t.

2: DMAP / CH₂Cl₂ / Ambient temperature

3: 76 percent / CuI / tetrahydrofuran / -15 °C

4: 1) Et₃N, 2) RuO₄ / 1) CH₂Cl₂, 0 deg C, 2) CCl₄-MeCN-H₂O, r.t.

With dmap; copper(l) iodide; ruthenium tetroxide; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4039(93)89027-N

Reference yield:

: 147461-20-9
(S)-(R)-4-Oxiranyl-butan-2-ol

: 147461-28-7
(4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: DMAP / CH₂Cl₂ / Ambient temperature

2: 76 percent / CuI / tetrahydrofuran / -15 °C

3: 1) Et₃N, 2) RuO₄ / 1) CH₂Cl₂, 0 deg C, 2) CCl₄-MeCN-H₂O, r.t.

With dmap; copper(l) iodide; ruthenium tetroxide; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4039(93)89027-N

Reference yield:

: 147461-21-0
tert-Butyl-((S)-1-methyl-3-(R)-oxiranyl-propoxy)-diphenyl-silane

: 147461-28-7
(4R,7S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methanesulfonyloxy-octanoic acid

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / CuI / tetrahydrofuran / -15 °C

2: 1) Et₃N, 2) RuO₄ / 1) CH₂Cl₂, 0 deg C, 2) CCl₄-MeCN-H₂O, r.t.

With copper(l) iodide; ruthenium tetroxide; triethylamine; In tetrahydrofuran;
DOI:10.1016/0040-4039(93)89027-N