(Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate

Base Information

• Chemical Name: (Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate
• CAS No.: 1158309-07-9
• Molecular Formula: C₁₈H₃₁O₅PSSi
• Molecular Weight: 418.566
• Mol file: 1158309-07-9.mol

Synonyms:(Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate

Chemical Property of (Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate

There total 1 articles about (Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

(Z)-(4-bromobut-2-enyl)trimethylsilane (1158308-98-5) + diethyl phenylsulfonylmethylphosphonate (56069-39-7) → (Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate (1158309-07-9)

Guidance literature:

diethyl phenylsulfonylmethylphosphonate; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; Inert atmosphere;

(Z)-(4-bromobut-2-enyl)trimethylsilane; With lithium iodide; In tetrahydrofuran; mineral oil; pentane; at 20 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.tetlet.2009.02.227

Reference yield: 83.0%

C17H19NO4S (1158308-83-8) + (Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate (1158309-07-9) → C31H39NO5S2Si + C31H39NO5S2Si (1158309-11-5)

Guidance literature:

(Z)-diethyl 1-(phenylsulfonyl)-5-(trimethylsilyl)pent-3-enylphosphonate; With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; Inert atmosphere;

C₁₇H₁₉NO₄S; In tetrahydrofuran; hexane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2009.02.227

upstream raw materials:

(Z)-(4-bromobut-2-enyl)trimethylsilane

diethyl phenylsulfonylmethylphosphonate

Downstream raw materials:

C₃₁H₃₉NO₅S₂Si