mer,cis-[RhCl₃(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)]

Base Information

• Chemical Name: mer,cis-[RhCl₃(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)]
• CAS No.: 887232-30-6
• Molecular Formula: C₃₄H₂₈Cl₃N₂P₂Rh
• Molecular Weight: 735.822

Synonyms:mer,cis-[RhCl₃(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)]

Chemical Property of mer,cis-[RhCl₃(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)]

Chemical Property:

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Technology Process of mer,cis-[RhCl₃(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)]

There total 1 articles about mer,cis-[RhCl₃(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

rhodium(III) chloride trihydrate + 2-(diphenylphosphino)pyridine (37943-90-1) → mer,cis-[RhCl3(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)] (887232-30-6)

Guidance literature:

In ethanol; dichloromethane; (inert atm., Schlenk) phosphine in CH2Cl2 was added with stirring to a warm soln. of RhCl3*3H2O in anhydrous ethanol, the mixt. was refluxed for2 h; reduced in vol., ppt. was filtered off, washed with diethyl ether, driedunder vac.; elem. anal.;

DOI:10.1021/ic051442k

Reference yield: 60.0%

sodium hexaflorophosphate + mer,cis-[RhCl3(diphenyl(2-pyridyl)phosphine-P,N)(diphenyl(2-pyridyl)phosphine-P)] (887232-30-6) → trans-[RhCl2(diphenyl(2-pyridyl)phosphine-P,N)2]PF6 (887232-32-8)

Guidance literature:

With AgNO₃; In acetone; byproducts: AgCl; (inert atm., Schlenk) AgNO3 was added to an acetone suspn. of complex, the mixt. was stirred in the dark for 20 min, AgCl was filtered off, NaPF6 in acetone was added, stirred for ca. 10 min; concd., under reduced pressure, diethyl ether was added, the solid was filtered, washed with diethyl ether, dried under vac,; elem. anal.;

DOI:10.1021/ic051442k

upstream raw materials:

2-(diphenylphosphino)pyridine

Downstream raw materials:

trans-[RhCl₂(diphenyl(2-pyridyl)phosphine-P,N)2]PF₆

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