dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate

Base Information

Chemical Name:dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate
CAS No.:1083094-30-7
Molecular Formula:C₁₈H₂₆O₄Si
Molecular Weight:334.488
Hs Code.:

Synonyms:dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate

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Technology Process of dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate

There total 1 articles about dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 1020210-70-1
dimethyl 2-(4-methylphenyl)-3-trimethylsilylcycloprop-2-ene-1,1-dicarboxylate

: 75-24-1
trimethylaluminum

: 1083094-30-7
dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate

Guidance literature:: With iron(III)-acetylacetonate; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 16h; stereoselective reaction;
DOI:10.1002/anie.200802391

Reference yield: 72.0%

: 1083094-30-7
dimethyl (Z)-2-[1-(4-methylphenyl)-2-(trimethylsilyl)prop-1-enyl]malonate

: 1083094-51-2
methyl (Z)-3-(4-methylphenyl)-4-(trimethylsilyl)pent-3-enoate

Guidance literature:: With sodium chloride; In water; N,N-dimethyl-formamide; at 130 ℃; for 1h; Microwave irradiation;
DOI:10.1002/anie.200802391