[5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾

Base Information

• Chemical Name: [5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾
• CAS No.: 210905-79-6
• Molecular Formula: C₅₀H₃₈I₂N₄Zn
• Molecular Weight: 1014.08
• Mol file: 210905-79-6.mol

Synonyms:[5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾

Chemical Property of [5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾

There total 1 articles about [5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

zinc(II) acetate dihydrate (5970-45-6) + p-(iodophenyl)carboxaldehyde (15164-44-0) + 5-(mesityl)dipyrromethane (159152-14-4) → [5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato(2-)]zinc(2+) (210905-79-6)

Guidance literature:

p-(iodophenyl)carboxaldehyde; 5-(mesityl)dipyrromethane; In dichloromethane; at 20 ℃; Inert atmosphere;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; Inert atmosphere;

zinc(II) acetate dihydrate; In chloroform; at 20 ℃; for 12h;

DOI:10.1021/acs.inorgchem.7b00740

Reference yield: 79.0%

[5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato(2-)]zinc(2+) (210905-79-6) + 2-(4-ethynyl-2,3,5,6-tetramethylphenyl)-9-(2,4,6-trimethylphenyl)-1,10-phenanthroline (1242155-87-8) → zinc(II) 5,15-bis{4-[2-(4-ethynyl-2,3,5,6-tetramethylphenyl)-9-(2,4,6-trimethylphenyl)[1,10]phenanthroline]phenyl}-10,20-bis(2,4,6-trimethylphenyl)porphyrin (1242155-86-7)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; tri tert-butylphosphoniumtetrafluoroborate; In N,N-dimethyl-formamide; at 75 ℃; for 15h; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.8b04437

Reference yield: 79.0%

[5,15-bis(4-iodophenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato(2-)]zinc(2+) (210905-79-6) + 9-ethynylanthracene (13752-40-4) → C82H56N4Zn

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 60 ℃; for 18h; Sealed tube;

DOI:10.1002/chem.202002877

upstream raw materials:

zinc(II) acetate dihydrate

p-(iodophenyl)carboxaldehyde

5-(mesityl)dipyrromethane

Downstream raw materials:

(((CH₃)3C₆H₂)2C₂₀H₈N₄(C₆H₄C₂C₁₂H₅N₂(C₆H₂(CH₃)3)(C₆(CH₃)4Br))2)Zn

[5,15-bis(4-([3-(3,3-diethyl-1-triazenyl)-5-(1,1-dimethylethyl)phenyl]ethynyl)phenyl)-10,20-bis(2,4,6-trimethylphenyl)porphyrinato^(2-)]zinc⁽²⁺⁾

[5,15-bis(2,4,6-trimethylphenyl)-10,20-bis[4-[(trimethylsilyl)ethynyl]phenyl]porphyrinato^(2-)]zinc⁽²⁺⁾

zinc(II) 5,15-bis[4-(2-(4-pyridyl)ethynyl)phenyl]-10,20-bis-[2,4,6-trimethylphenyl]porphyrin