3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Base Information

Chemical Name:3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate
CAS No.:914955-21-8
Molecular Formula:C₄₅H₅₁N₃O₁₃
Molecular Weight:841.912
Hs Code.:

Synonyms:3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Suppliers and Price of 3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

There total 11 articles about 3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 914955-27-4
methyl (phenyl 2,3-di-O-benzyl-1-thio-α-D-mannopyranoside)uronate

: 914955-21-8
3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / pyridine / dioxane / 20 °C

2: 78 percent / N-iodosuccinimide; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / -40 - 20 °C

3: 95 percent / N₂H₄*H₂O / pyridine; acetic acid / 0.5 h / 20 °C

With pyridine; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; hydrazine hydrate; In 1,4-dioxane; pyridine; dichloromethane; acetic acid;
DOI:10.1021/ja064787q

Reference yield:

: 914955-24-1
phenyl 2,3-di-O-benzyl-1-thio-α-D-mannopyranosiduronic acid

: 914955-21-8
3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / K₂CO₃ / dimethylformamide / 10 h / 20 °C

2: 86 percent / pyridine / dioxane / 20 °C

3: 78 percent / N-iodosuccinimide; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / -40 - 20 °C

4: 95 percent / N₂H₄*H₂O / pyridine; acetic acid / 0.5 h / 20 °C

With pyridine; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; potassium carbonate; hydrazine hydrate; In 1,4-dioxane; pyridine; dichloromethane; acetic acid; N,N-dimethyl-formamide;
DOI:10.1021/ja064787q

Reference yield:

: 904745-28-4
methyl (phenyl 4-O-acetyl-2,3-di-O-benzyl-1-thio-α-D-mannopyranoside)uronate

: 914955-21-8
3-azidopropyl ((methyl 2,3-di-O-benzyl-4-O-(methyl 2,3-di-O-benzyl-β-D-mannopyranosyl)uronate)-β-D-mannopyranoside)uronate

Guidance literature:: Multi-step reaction with 4 steps

1.1: Ph₂SO; tri-tert-butylpyrimidine; triflic acid anhydride / CH₂Cl₂ / 0.25 h / -40 °C

1.2: CH₂Cl₂ / -80 - 20 °C

1.3: 80 percent / pyridine / CH₂Cl₂ / 10 h / 20 °C

2.1: 60 percent / NaOMe / methanol / 6 h / 20 °C

3.1: 78 percent / N-iodosuccinimide; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / -40 - 20 °C

4.1: 95 percent / N₂H₄*H₂O / pyridine; acetic acid / 0.5 h / 20 °C

With N-iodo-succinimide; trifluoromethylsulfonic anhydride; trimethylsilyl trifluoromethanesulfonate; 1,1'-sulfinylbisbenzene; 2,4,5-tri-tert-butylpyrimidine; sodium methylate; hydrazine hydrate; In pyridine; methanol; dichloromethane; acetic acid;
DOI:10.1021/ja064787q